# US 5,688,564 A · Process for the preparation and coating of a surface > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,688,564 A - Document ID: US5688564A - Status: Granted - Kind: A - Application number: 08/520,127 - Filed: 1995-08-28 - Granted: 1997-11-18 - Earliest claimed: 1992-07-23 - Assignees: Institut Polytechnique de Sevenans; Irepa Laser - Inventors: Christian Louis Michel Coddet; Thierry Marchione - Web page: https://patentgrep.com/patent/US5688564A ## CPC - C23C 4/02: Pretreatment of the material to be coated, e.g. for coating on selected surface areas - C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04) ## Abstract A process and apparatus for the preparation and coating of the surface of a substrate by thermal projection, in which the surface of the substrate is progressively subjected to laser irradiation thereby at least partially to eliminate a superficial contaminating film on the surface of the substrate, and then there is projected by a thermal projection device a deposit material on the surface thus prepared immediately after the preparation. The surface of the substrate is subjected to successive laser and thermal projection treatments thereby to lay down on the surface a plurality of layers of deposit material. The substrate can be cylindrical, and can be rotated about its axis while continuously applying laser radiation and thermal projection thereto, with the substrate rotating in a direction such that the surface of the substrate is subjected first to laser radiation and subsequently to thermal projection. The laser is a pulsed laser. ## Claims ### Claim 1 A process for the preparation and coating of a surface of a substrate by thermal projection, comprising: progressively subjecting a surface of a substrate to laser irradiation thereby at least partially to eliminate a superficial contaminating film on the surface of the substrate and to cause the surface to have an increased roughness; projecting by means of a thermal projection device a deposit material on the surface thus prepared immediately after said preparation so as to result in an overlapping of the impact zones of the laser beam and of the projected deposit material; and subjecting the surface of the substrate to successive laser and thermal projection treatments to lay down on the surface a plurality of layers of the same said deposit material, thereby to decrease substantially the porosity and to increase the adherence of previously deposited said layers of deposit material. ### Claim 2 (depends on 1) A process as claimed in claim 1, wherein the substrate is cylindrical, and rotating the substrate about its axis while continuously applying laser radiation and thermal projection thereto, with the substrate rotating in a direction such that the surface of the substrate is subjected first to said laser radiation and subsequently to said thermal projection. ### Claim 3 (depends on 2) A process as claimed in claim 2, wherein said laser radiation and said thermal deposition are effected in directions substantially perpendicular to the surface of the substrate, said directions being disposed at a small acute angle to each other. ### Claim 4 (depends on 1) A process as claimed in claim 1, wherein said deposit material is metal oxide. ### Claim 5 (depends on 4) A process as claimed in claim 4, wherein said metal oxide is aluminum oxide and titanium oxide. ### Claim 6 (depends on 1) A process as claimed in claim 1, wherein said substrate is an aluminum alloy. ### Claim 7 A process for the preparation and coating of a surface of a substrate by thermal projection, comprising: progressively subjecting a surface of a substrate to laser irradiation comprised of successive laser pulses thereby at least partially to eliminate a superficial contaminating film on the surface of the substrate and to modify the morphology of a subjacent surface of the substrate so that the subjacent surface has an increased roughness; projecting by means of a thermal projection device a deposit material on the surface thus prepared immediately after said preparation and in synchronism therewith so as to result in an overlapping of the impact zones of the laser beam and of the projected deposit material; and obtaining a coating by application of several superposed layers of deposit material by successive depositions, said coating being obtained by providing for a given zone before deposit of each new layer, a preparation and modification by laser beam of a deposited layer, such that with the continuous action of the laser during thermal projection, the successive preparation of each layer surface results in an improvement of the properties of the deposit and a compaction of the preceding layers. ### Claim 8 (depends on 7) A process as claimed in claim 7 wherein the substrate is cylindrical, and rotating the substrate about its axis while continuously applying laser radiation and thermal projection thereto, with the substrate rotating in a direction such that the surface of the substrate is subjected first to said laser radiation and subsequently to said thermal projection. ### Claim 9 (depends on 8) A process as claimed in claim 8 wherein said laser radiation and said thermal deposition are effected in directions substantially perpendicular to the surface of the substrate, said directions being disposed at a small acute angle to each other. ### Claim 10 (depends on 9) A process as claimed in claim 9, wherein said deposit material is metal oxide. ### Claim 11 (depends on 10) A process as claimed in claim 10, wherein said metal oxide is aluminum oxide and titanium oxide. ### Claim 12 (depends on 7) A process as claimed in claim 7, wherein said substrate is an aluminum alloy.