US 5,686,390 AGranted

Iminosulfonylurea derivatives and herbicides

AssigneeNissan Chemical Industries, Ltd.

InventorsKenzi Makino, Shigeaki Akiyama, Hideaki Suzuki, Takeshi Nagaoka, Toshio Niki, Koichi Suzuki, Tsutomu Nawamaki, Shigeomi Watanabe, Kimihiro Ishikawa

Life of this patent

Estimating the term…

Abstract

An iminosulfonylurea compound or a salt thereof which is useful as a herbicide and growth control agent against weeds.

Claims11

Dependent claims

A compound of the formula:

##STR778## wherein Q is:
##STR779## each of R.sup.a1, R.sup.b1, R.sup.c1, R.sup.d1, R.sup.f1 are, independently, a C1-8 alkyl group;
a C.sub.3-7 cycloalkyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 cycloalkyl group;
a C.sub.3-7 cycloalkenyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 cycloalkenyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-6 alkenyloxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-6 alkynyloxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or polyhalogeno C.sub.2-6 alkenyloxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.2-6 alkynyloxy group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylthio group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfonyl group, a mono-, di- or poly-halogeno C.sub.1-8 alkyl group;
a mono-, di- or poly-halogeno C.sub.2-8 alkenyl group;
a mono-, di- or poly-halogen C.sub.2-8 alkynyl group;
a C.sub.1-6 alkyl group substituted by a cyano group;
a C.sub.2-6 alkenyl group substituted by a cyano group;
a C.sub.2-6 alkynyl group substituted by a cyano group;
a C.sub.1-6 alkyl group substituted by a nitro group;
a C.sub.2-6 alkenyl group substituted by a nitro group;
a C.sub.2-6 alkynyl group substituted by a nitro group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-6 alkenyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-6 alkynyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 alkenylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 alkynylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkoxy group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylthio group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylsulfinyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylsulfonyl group;
a C.sub.2-6 alkenyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.2-6 alkynyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxysulfamoyl group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)sulfamoyl group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)sulfamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbamoyl group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)carbamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkoxycarbamoyl group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)carbamoyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylamino group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxyamino group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)amino group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)amino group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.2-7 alkylcarbonyl)-N-(C.sub.1-6 alkyl)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.2-7 alkylcarbonyl)-N-(C.sub.1-6 alkoxy)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-6 alkylsulfonyl)-N-(C.sub.1-6 alkyl)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-6 alkylsulfonyl)-N-(C.sub.1-6 alkoxy)amino group, a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-7 alkenyl group substituted by a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-6 alkynyl group substituted by a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenoxy group, provided that such a phenoxy group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylthio group, provided that such a phenylthio group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylsulfinyl group, provided that such a phenylsulfinyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylsulfonyl group, provided that such a phenylsulfonyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a benzyloxy group (provided that the phenyl group of such a benzyloxy group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylthio group, provided that the phenyl group of such a benzylthio group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylsulfinyl group, provided that the phenyl group of such a benzylsulfinyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylsulfonyl group;
a C.sub.1-6 alkyl group substituted by a benzylsulfonyl group which is substituted on the phenyl group of the benzylsulfonyl group by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylcarbonyl group wherein the phenylcarbonyl group is substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylcarbonyl wherein the phenyl ring of the benzylcarbonyl group is substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by an amino group substituted by a C.sub.1-4 alkylsulfonyl group;
or a C.sub.1-6 alkyl group substituted by an amino group substituted by a C.sub.2-4 alkylcarbonyl group,
R.sup.b2 is a hydrogen atom, a C.sub.1-6 alkyl group, a mono-, di- or poly-halogeno C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group, a mono-, di or poly-halogeno C.sub.1-6 alkoxy group, a C.sub.1-6 alkylthio group, a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkylsulfonyl group, a C.sub.2-7 alkoxycarbonyl group, a C.sub.2-7 alkylcarbonyl group, a halogen atom, a nitro group, a cyano group, or a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
each of R.sup.a4 and R.sup.a5 which are independent of each other, is a hydrogen atom, a C.sub.1-8 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, or a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
R.sup.a6 is C.sub.1-8 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group or a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group, consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
R.sup.b3 is a hydrogen atom, a C.sub.1-6 alkyl group, a C.sub.2-6 alkenyl group or a C.sub.2-6 alkynyl group;
each of R.sup.b4 and R.sup.b5 are, independently, a hydrogen atom or a C.sub.1-6 alkyl group;
each of R.sup.c2, R.sup.c3, R.sup.d2, R.sup.d3, R.sup.d4, R.sup.f5 and R.sup.f6 are, independently, a hydrogen atom, a C.sub.1-8 alkyl group, a mono-, di- or poly-halogeno C.sub.1-6 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a phenyl group or a phenyl group substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
R.sup.d5 a C.sub.1-8 alkyl group, a mono-, di- or poly-halogeno C.sub.1-6 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a phenyl group or a phenyl group substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
R.sup.d6 and R.sup.f2 are, independently, a C.sub.1-8 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylthio group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfonyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbonyl group, a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcorbonyl group, a C.sub.1-6 alkyl group substituted by a cyano group, a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy, and a C.sub.2-7 alkoxycarbonyl group;
or a C.sub.1-6 alkyl group substituted by a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
X is an oxygen atom or a sulfur atom,
L is a hydrogen atom, a C.sub.1-6 alkyl group, a C.sub.2-6 alkenyl group or a C.sub.2-6 alkynyl group,
G is ##STR780## A is a nitrogen atom, and each of B and D are, independently, a C.sub.1-4 alkyl group, a C.sub.1-4 alkoxy group, a mono-, di- or poly-halogeno C.sub.1-4 alkyl group, a mono-, di- or poly-halogeno C.sub.1-4 alkoxy group, a halogen atom, a C.sub.1-4 alkylamino group or a di(C.sub.1-3 alkyl)amino group.

64 more elements

A compound of the formula:

##STR786## where Q is:
##STR787## each of R.sup.a1, R.sup.c1, and R.sup.f1 are, independently, a C.sub.1-8 alkyl group;
a C.sub.3-7 cycloalkyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 cycloalkyl group;
a C.sub.3-7 cycloalkenyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 cycloalkenyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-6 alkenyloxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-6 alkynyloxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or polyhalogeno C.sub.2-6 alkenyloxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.2-6 alkynyloxy group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylthio group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfonyl group, a mono-, di- or poly-halogeno C.sub.1-8 alkyl group;
a mono-, di- or poly-halogeno C.sub.2-8 alkenyl group;
a mono-, di- or poly-halogen C.sub.2-8 alkynyl group;
a C.sub.1-6 alkyl group substituted by a cyano group;
a C.sub.2-6 alkenyl group substituted by a cyano group;
a C.sub.2-6 alkynyl group substituted by a cyano group;
a C.sub.1-6 alkyl group substituted by a nitro group;
a C.sub.2-6 alkenyl group substituted by a nitro group;
a C.sub.2-6 alkynyl group substituted by a nitro group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-6 alkenyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-6 alkynyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 alkenylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 alkynylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkoxy group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylthio group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylsulfinyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylsulfonyl group;
a C.sub.2-6 alkenyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.2-6 alkynyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxysulfamoyl group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)sulfamoyl group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)sulfamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbamoyl group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)carbamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkoxycarbamoyl group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)carbamoyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylamino group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxyamino group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)amino group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)amino group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.2-7 alkylcarbonyl)-N-(C.sub.1-6 alkyl)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.2-7 alkylcarbonyl)-N-(C.sub.1-6 alkoxy)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-6 alkylsulfonyl)-N-(C.sub.1-6 alkyl)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-6 alkylsulfonyl)-N-(C.sub.1-6 alkoxy)amino group, a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.2-7 alkenyl group substituted by a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.2-6 alkynyl group substituted by a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a phenoxy group (provided that such a phenoxy group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a phenylthio group (provided that such a phenylthio group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a phenylsulfinyl group (provided that such a phenylsulfinyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a phenylsulfonyl group (provided that such a phenylsulfonyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a benzyloxy group (provided that the phenyl group of such a benzyloxy group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a benzylthio group (provided that the phenyl group of such a benzylthio group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a benzylsulfinyl group (provided that the phenyl group of such a benzylsulfinyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a benzylsulfonyl group;
a C.sub.1-6 alkyl group substituted by a benzylsulfonyl group which is substituted on the phenyl group of the benzylsulfonyl group by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylcarbonyl group wherein the phenylcarbonyl group is substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylcarbonyl wherein the phenyl ring of the benzylcarbonyl group is substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by an amino group substituted by a C.sub.1-4 alkylsulfonyl group;
or a C.sub.1-6 alkyl group substituted by an amino group substituted by a C.sub.2-4 alkylcarbonyl group,
each of R.sup.a2, R.sup.a3, R.sup.c7, R.sup.c8, R.sup.f3 and R.sup.f4 are, independently, a hydrogen atom, a C.sub.1-6 alkyl group, a mono-, di- or poly-halogen C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group, a mono-, di or poly-halogeno C.sub.1-6 alkoxy group, a C.sub.1-6 alkylthio group, a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkylsulfonyl group, a C.sub.2-7 alkoxycarbonyl group, a C.sub.2-7 alkylcarbonyl group, a halogen atom, a nitro group, a cyano group, or a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group);
R.sup.a6 is C.sub.1-8 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group or a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group, consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group),
R.sup.f2 is a C.sub.1-8 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylthio group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfonyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbonyl group, a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbonyl group, a C.sub.1-6 alkyl group substituted by a cyano group, a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl a group, C.sub.1-6 alkoxy group, and a C.sub.2-7 alkoxycarbonyl group), or a C.sub.1-6 alkyl group substituted by a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group),
X is an oxygen atom or a sulfur atom,
L is a hydrogen atom, a C.sub.1-6 alkyl group, a C.sub.2-6 alkenyl group or a C.sub.2-6 alkynyl group,
G is ##STR788## A is a nitrogen atom, and each of B and D are, independently, a C.sub.1-4 alkyl group, a C.sub.1-4 alkoxy group, a mono-, di- or poly-halogeno C.sub.1-4 alkyl group, a mono-, di- or poly-halogeno C.sub.1-4 alkoxy group, a halogen atom, a C.sub.1-4 alkylamino group or a di(C.sub.1-3 alkyl)amino group.

49 more elements

Dependencies are inferred from the claim text.

Facts

Application: 08/573,549Filed 15 Dec 1995 · division
Priority: JP 3-15810628 Jun 1991
Granted: 11 Nov 1997
Term ends: Not estimatedThe source records don’t support an estimate.

Classification4 codes

C07D 521/00
Heterocyclic compounds containing unspecified hetero rings
A01N 47/36
Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<: containing the group >N—CO—N< directly attached to at least one heterocyclic ring;…
C07D
Heterocyclic compounds
A01N
Preservation of bodies of humans or animals or plants or parts thereof

Family

Serial170,222Parent of this division · filed 15 Apr 1994
US 5,500,466 AParent of this division
US 5,686,390 AThis patent

From the US filing history. Foreign family members aren’t listed.

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A compound of the formula:

##STR778## wherein Q is:
##STR779## each of R.sup.a1, R.sup.b1, R.sup.c1, R.sup.d1, R.sup.f1 are, independently, a C1-8 alkyl group;
a C.sub.3-7 cycloalkyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 cycloalkyl group;
a C.sub.3-7 cycloalkenyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 cycloalkenyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-6 alkenyloxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-6 alkynyloxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or polyhalogeno C.sub.2-6 alkenyloxy group, a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.2-6 alkynyloxy group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylthio group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfonyl group, a mono-, di- or poly-halogeno C.sub.1-8 alkyl group;
a mono-, di- or poly-halogeno C.sub.2-8 alkenyl group;
a mono-, di- or poly-halogen C.sub.2-8 alkynyl group;
a C.sub.1-6 alkyl group substituted by a cyano group;
a C.sub.2-6 alkenyl group substituted by a cyano group;
a C.sub.2-6 alkynyl group substituted by a cyano group;
a C.sub.1-6 alkyl group substituted by a nitro group;
a C.sub.2-6 alkenyl group substituted by a nitro group;
a C.sub.2-6 alkynyl group substituted by a nitro group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-6 alkenyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-6 alkynyl group substituted by a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a mono-, di- or poly-halogeno C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 alkenylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.3-7 alkynylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkoxy group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylthio group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylsulfinyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-5 alkylcarbonyl group substituted by a C.sub.1-4 alkylsulfonyl group;
a C.sub.2-6 alkenyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.2-6 alkynyl group substituted by a C.sub.2-7 alkylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxysulfamoyl group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)sulfamoyl group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)sulfamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbamoyl group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)carbamoyl group;
a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkoxycarbamoyl group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)carbamoyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylamino group;
a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxyamino group;
a C.sub.1-6 alkyl group substituted by a di(C.sub.1-3 alkyl)amino group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-3 alkyl)-N-(C.sub.1-3 alkoxy)amino group;
a C.sub.1-6 alkyl group substituted by an N-(C.sub.2-7 alkylcarbonyl)-N-(C.sub.1-6 alkyl)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.2-7 alkylcarbonyl)-N-(C.sub.1-6 alkoxy)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-6 alkylsulfonyl)-N-(C.sub.1-6 alkyl)amino group, a C.sub.1-6 alkyl group substituted by an N-(C.sub.1-6 alkylsulfonyl)-N-(C.sub.1-6 alkoxy)amino group, a phenyl group (provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-7 alkenyl group substituted by a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.2-6 alkynyl group substituted by a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenoxy group, provided that such a phenoxy group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylthio group, provided that such a phenylthio group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylsulfinyl group, provided that such a phenylsulfinyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylsulfonyl group, provided that such a phenylsulfonyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group), a C.sub.1-6 alkyl group substituted by a benzyloxy group (provided that the phenyl group of such a benzyloxy group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylthio group, provided that the phenyl group of such a benzylthio group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylsulfinyl group, provided that the phenyl group of such a benzylsulfinyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylsulfonyl group;
a C.sub.1-6 alkyl group substituted by a benzylsulfonyl group which is substituted on the phenyl group of the benzylsulfonyl group by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a phenylcarbonyl group wherein the phenylcarbonyl group is substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylcarbonyl group;
a C.sub.1-6 alkyl group substituted by a benzylcarbonyl wherein the phenyl ring of the benzylcarbonyl group is substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
a C.sub.1-6 alkyl group substituted by an amino group substituted by a C.sub.1-4 alkylsulfonyl group;
or a C.sub.1-6 alkyl group substituted by an amino group substituted by a C.sub.2-4 alkylcarbonyl group,
R.sup.b2 is a hydrogen atom, a C.sub.1-6 alkyl group, a mono-, di- or poly-halogeno C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group, a mono-, di or poly-halogeno C.sub.1-6 alkoxy group, a C.sub.1-6 alkylthio group, a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkylsulfonyl group, a C.sub.2-7 alkoxycarbonyl group, a C.sub.2-7 alkylcarbonyl group, a halogen atom, a nitro group, a cyano group, or a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
each of R.sup.a4 and R.sup.a5 which are independent of each other, is a hydrogen atom, a C.sub.1-8 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, or a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
R.sup.a6 is C.sub.1-8 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group or a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group, consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
R.sup.b3 is a hydrogen atom, a C.sub.1-6 alkyl group, a C.sub.2-6 alkenyl group or a C.sub.2-6 alkynyl group;
each of R.sup.b4 and R.sup.b5 are, independently, a hydrogen atom or a C.sub.1-6 alkyl group;
each of R.sup.c2, R.sup.c3, R.sup.d2, R.sup.d3, R.sup.d4, R.sup.f5 and R.sup.f6 are, independently, a hydrogen atom, a C.sub.1-8 alkyl group, a mono-, di- or poly-halogeno C.sub.1-6 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a phenyl group or a phenyl group substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
R.sup.d5 a C.sub.1-8 alkyl group, a mono-, di- or poly-halogeno C.sub.1-6 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a phenyl group or a phenyl group substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
R.sup.d6 and R.sup.f2 are, independently, a C.sub.1-8 alkyl group, a C.sub.2-8 alkenyl group, a C.sub.2-8 alkynyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylthio group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfinyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkylsulfonyl group, a C.sub.1-6 alkyl group substituted by a C.sub.1-6 alkoxy group, a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcarbonyl group, a C.sub.1-6 alkyl group substituted by a C.sub.2-7 alkylcorbonyl group, a C.sub.1-6 alkyl group substituted by a cyano group, a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy, and a C.sub.2-7 alkoxycarbonyl group;
or a C.sub.1-6 alkyl group substituted by a phenyl group, provided that such a phenyl group may be substituted by one or more substituents selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, a C.sub.1-6 alkyl group, a C.sub.1-6 alkoxy group and a C.sub.2-7 alkoxycarbonyl group;
X is an oxygen atom or a sulfur atom,
L is a hydrogen atom, a C.sub.1-6 alkyl group, a C.sub.2-6 alkenyl group or a C.sub.2-6 alkynyl group,
G is ##STR780## A is a nitrogen atom, and each of B and D are, independently, a C.sub.1-4 alkyl group, a C.sub.1-4 alkoxy group, a mono-, di- or poly-halogeno C.sub.1-4 alkyl group, a mono-, di- or poly-halogeno C.sub.1-4 alkoxy group, a halogen atom, a C.sub.1-4 alkylamino group or a di(C.sub.1-3 alkyl)amino group.

64 more elements

Facts

Application

08/573,549Filed 15 Dec 1995 · division

Priority

JP 3-15810628 Jun 1991

Granted

11 Nov 1997

Term ends

Not estimatedThe source records don’t support an estimate.

Classification4 codes

C07D 521/00
Heterocyclic compounds containing unspecified hetero rings
A01N 47/36
Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<: containing the group >N—CO—N< directly attached to at least one heterocyclic ring;…
C07D
Heterocyclic compounds
A01N
Preservation of bodies of humans or animals or plants or parts thereof