# US 5,684,459 A · Curvature-reduction annealing of amorphous metal alloy ribbon > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,684,459 A - Document ID: US5684459A - Status: Granted - Kind: A - Application number: 08/538,026 - Filed: 1995-10-02 - Granted: 1997-11-04 - Earliest claimed: 1995-10-02 - Assignees: Sensormatic Electronics Corporation - Inventors: Nen-chin Liu; Larry Speciale - Web page: https://patentgrep.com/patent/US5684459A ## CPC - G08B 13/2408: {using ferromagnetic tags} - G08B 13/244: {Tag manufacturing, e.g. continuous manufacturing processes} - G08B 13/2442: {Tag materials and material properties thereof, e.g. magnetic material details} - G08B: SIGNALLING SYSTEMS, e.g. PERSONAL CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS ## Abstract A longitudinal curvature in an amorphous metal alloy ribbon is reduced by heat-treatment. While the heat-treatment occurs, the alloy ribbon is bent "backwards" against the longitudinal curvature, to reduce the amount of heat-treatment required. The process is carried out continuously by transporting the alloy ribbon from reel to reel, while wrapping the ribbon around a heated roller. Using a discrete strip cut from the alloy ribbon subjected to the curvature-reducing process, a magnetomechanical EAS marker is constructed that has a relatively low profile, while retaining desired magnetic properties. ## Claims ### Claim 1 A method of forming magnetostrictive elements for use in a magnetomechanical electronic article surveillance marker, comprising the steps of: providing a continuous strip of an amorphous metal alloy; heat-treating the continuous amorphous alloy strip at a heating location while continuously transporting the strip past the heating location; applying a curvature to the continuous amorphous alloy strip, said curvature being applied by wrapping said strip around a curved element at said heating location; and cutting the heat-treated strip into discrete strips each having a predetermined length. ### Claim 2 (depends on 1) A method according to claim 1, wherein said curvature is applied to the continuous amorphous alloy strip in a longitudinal direction of the strip. ### Claim 3 (depends on 2) A method according to claim 2, wherein said steps of heat-treating the continuous amorphous alloy strip and applying the curvature thereto are performed by wrapping the strip around a heated roller. ### Claim 4 (depends on 2) A method according to claim 2, wherein the curvature is applied to the strip at an orientation opposite to an orientation of longitudinal curvature exhibited by the strip prior to said heat-treating step. ### Claim 5 (depends on 1) A method according to claim 1, wherein the continuous strip comprises an alloy of iron, nickel, molybdenum and boron. ### Claim 6 (depends on 5) A method according to claim 5, wherein the continuous strip essentially has the composition Fe.sub.40 Ni.sub.38 Mo.sub.4 B.sub.18. ### Claim 7 (depends on 1) A method according to claim 1, wherein said heat-treating step is performed at a temperature of at least 300.degree. C. ### Claim 8 An apparatus for heat-treating a continuous strip of an amorphous metal alloy, comprising: a curved element around which the continuous amorphous alloy strip is wrapped; heating means for applying heat to the continuous amorphous alloy strip at the curved element; and transport means for continuously transporting the strip along a path past said heating means. ### Claim 9 (depends on 8) An apparatus according to claim 8, wherein said curved element is positioned relative to said path so as to apply a curvature to the continuous amorphous alloy strip in a longitudinal direction of the strip. ### Claim 10 (depends on 9) An apparatus according to claim 9, wherein said curved element is a heated roller. ### Claim 11 (depends on 8) An apparatus according to claim 8, further comprising: a supply reel, from which the continuous strip is transported towards said heating means; and a take-up reel, towards which the continuous strip is transported from said heating means. ### Claim 12 (depends on 11) An apparatus according to claim 11, wherein said transport means includes a capstan and a pinch roller, both interposed between said heating means and said take-up reel, the continuous strip being engaged between said capstan and said pinch roller for being driven by said capstan towards said take-up reel. ### Claim 13 A magnetostrictive element for use in a magnetomechanical electronic article surveillance marker, formed by heat-treating a continuous strip of an amorphous metal alloy at a curved element around which the strip is wrapped, and then cutting the heat-treated continuous strip into discrete strips. ### Claim 14 (depends on 13) A magnetostrictive element according to claim 13, wherein said heat-treatment is performed so as to reduce a degree of longitudinal curvature exhibited by the continuous strip prior to said heat-treatment. ### Claim 15 (depends on 13) A magnetostrictive element according to claim 13, comprising an alloy of iron, nickel, molybdenum and boron. ### Claim 16 (depends on 15) A magnetostrictive element according to claim 15, essentially having the composition Fe.sub.40 Ni.sub.38 Mo.sub.4 B.sub.38. ### Claim 17 A marker for use in a magnetomechanical electronic article surveillance system, comprising a discrete amorphous magnetostrictive strip formed by heat-treating a continuous strip of an amorphous metal alloy at a curved element around which the continuous strip is wrapped and then cutting the heat-treated continuous strip. ### Claim 18 (depends on 17) A marker according to claim 17, wherein said heat-treatment is performed so as to reduce a degree of longitudinal curvature exhibited by the continuous strip prior to said heat-treatment. ### Claim 19 (depends on 17) A marker according to claim 17, wherein said discrete amorphous magnetostrictive strip comprises an alloy of iron, nickel, molybdenum and boron. ### Claim 20 (depends on 17) A marker according to claim 17, wherein said discrete amorphous magnetostrictive strip essentially has the composition Fe.sub.40 Ni.sub.38 Mo.sub.4 B.sub.18. ### Claim 21 A magnetomechanical electronic article surveillance system comprising: (a) generating means for generating an electromagnetic field alternating at a selected frequency in an interrogation zone, said generating means including an interrogation coil; (b) a marker secured to an article appointed for passage through said interrogation zone, said marker including an amorphous magnetostrictive element formed by heat-treating a continuous strip of an amorphous metal alloy at a curved element around which the strip is wrapped, and then cutting the heat-treated continuous strip into discrete strips, said marker also including a biasing element located adjacent to said magnetostrictive element, said biasing element being magnetically biased to cause said magnetostrictive element to be mechanically resonant when exposed to said alternating field; and (c) detecting means for detecting said mechanical resonance of said magnetostrictive element. ### Claim 22 (depends on 21) A magnetomechanical electronic article surveillance system according to claim 21, wherein said magnetostrictive element comprises an alloy of iron, nickel, molybdenum and boron. ### Claim 23 (depends on 22) A magnetomechanical electronic article surveillance system according to claim 22, wherein said magnetostrictive element essentially has the composition Fe.sub.40 Ni.sub.38 Mo.sub.4 B.sub.18. ### Claim 24 A marker for use in a magnetomechanical electronic article surveillance system, comprising a discrete amorphous strip essentially having the composition Fe.sub.40 Ni.sub.38 Mo.sub.4 B.sub.18, the marker having an overall thickness of less than 0.065 inches. ### Claim 25 (depends on 24) A marker according to claim 24, wherein the marker has an overall thickness of substantially 0.055 inches. ### Claim 26 (depends on 24) A marker according to claim 24, wherein the marker has an overall thickness of substantially 0.037 inches. ### Claim 27 A method of reducing a degree of longitudinal curvature in an amorphous metal alloy strip having a longitudinal axis, the method comprising the steps of: applying a curvature to the alloy strip along the longitudinal axis of the strip and at an orientation opposite to a longitudinal curvature exhibited by the strip prior to said application of curvature, said curvature being applied by wrapping said strip around a curved element; and heat-treating the strip at the curved element. ### Claim 28 (depends on 27) A method according to claim 27, wherein said amorphous metal alloy strip is a continuous ribbon and said heat-treating and curvature-applying steps are performed while transporting the alloy strip from a supply reel to a take-up reel. ### Claim 29 (depends on 27) A method according to claim 27, wherein the alloy strip comprises an alloy of iron, nickel, molybdenum and boron. ### Claim 30 (depends on 29) A method according to claim 29, wherein the alloy strip essentially has the composition Fe.sub.40 Ni.sub.38 Mo.sub.4 B.sub.18. ### Claim 31 A method of forming magnetostrictive elements for use in a magnetomechanical electronic article surveillance marker, comprising the steps of: providing a continuous strip of an amorphous metal alloy; continuously supplying the alloy strip to a heating location; heat-treating the alloy strip at the heating location while continuously transporting the alloy strip in a curved path at the heating location; and cutting the heat-treated strip into discrete strips each having a predetermined length.