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US 5,683,625 AGranted
Method of preparing microemulsions
AssigneeGeneral Electric Company
InventorsMarianne D. Berthiaume, James H. Merrifield
Life of this patent
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Abstract
Microemulsion compositions comprising low amino content microemulsifiable silicones and a surfactant having a high phase inversion temperature, the microemulsions formed therewith, a means for preparing said microemulsions, and personal care products comprising said microemulsions.
Claims11
A process for preparing a transparent microemulsion comprising:
- (a) preparing a blend of silicones comprising a low silicone content microemulsifiable silicone having the formula:
- M(R.sub.a Q.sub.b SiO.sub.(4-a-b)/2).sub.x (R.sub.c SiO.sub.(4-c)/2).sub.y M
- wherein R is a hydrocarbon or hydrocarbon radical having from 1 to about 6 carbon atoms, Q is a polar radical having the general formula --R.sup.1 HZ, wherein R.sup.1 is a divalent linking group bound to hydrogen ,and a radical Z wherein R.sup.1 is comprised of carbon and hydrogen atoms;
- carbon, hydrogen and oxygen atoms, or carbon, hydrogen and nitrogen atoms;
- and Z is an amino containing radical having the formula:
- --N(CH.sub.2).sub.z (CH.sub.2).sub.zz NH
- wherein z is one or greater and zz is zero or greater subject to the limitation such that when zz is zero Z has the formula:
- --NH(CH.sub.2).sub.z NH.sub.2
- wherein z is one or greater;
- a ranges from about 0 to about 2, b ranges from about 1 to about 3 such that a+b is less than or equal to 3, and c is a number in the range of from about 1 to about 3;
- and x is a number in the range of from 1 to about 20 and y is a number in the range from about 20 to about 800, and M is a silicone endstopping group;
- (b) adding a surfactant having a phase inversion temperature ranging from about 45.degree. to about 95.degree. C.;
- (c) heating said silicone and said surfactant to a temperature ranging from about 45.degree. C. to 95.degree. C. wherein the temperature is a temperature below the phase inversion temperature of the surfactant;
- (d) adding part I water;
- (e) adding an acid;
- and
- (f) adding part II water, whereby said microemulsion has an ASTM D871 haze number below about 150.
14 more elements
Dependencies are inferred from the claim text.