Process for the production of color- and odor-stable quaternized fatty acid triethanolamine ester salts
AssigneeHenkel Kommanditgesellschaft auf Aktien
InventorsOriol Ponsati Obiols, Joaquim Bigorra Llosas
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Abstract
A process for the production of color- and odor-stable quaternized fatty acid triethanolamine ester salts comprising the steps of A) partially or fully esterifying triethanolamine with at least one fatty acid in the presence of hypophosphorous acid; B) adding a peroxide compound and an alkali metal boranate to the esterification product from step A); and C) quaternizing the esterification product with an alkyl halide, a (di)alkyl sulfate or an alkylene oxide in the presence of a phenol derivative and a hydroxycarboxylic acid.
Claims20
A process for the production of at least one color- and odor-stable quaternized fatty acid triethanolamine ester salt corresponding to formula (I):
- ##STR2## wherein R.sup.1 CO is an acyl radical containing 6 to 22 carbon atoms,
- R.sup.2 and R.sup.3 independently of one another represent hydrogen or have the same meaning as R.sup.1 CO,
- R.sup.4 is an alkyl radical containing 1 to 4 carbon atoms or a (CH.sub.2 CH.sub.2 O).sub.q H group, in which q is a number from 1 to 12,
- m, n and p together=0 or a number of 1 to 10 and
- X is a halide, alkyl sulfate or alkyl phosphate, comprising the steps of
- A) partially or fully esterifying triethanolamine with at least one fatty acid of the formula R.sup.1 COOH wherein R.sup.1 CO is as defined above in the presence of hypophosphorous acid;
- B) adding a peroxide compound and an alkali metal boranate to the esterification product from step A);
- and
- C) quaternizing the esterification product with an alkyl halide, a (di)alkyl sulfate or an alkylene oxide in the presence of a phenol derivative and a hydroxycarboxylic acid, wherein where an alkylene oxide is used as the quaternizing agent, a (di)alkyl phosphate is also present.
Dependencies are inferred from the claim text.