Depolymerization of polyamides
AssigneeDsm N.V.
InventorsJan A. J. Hendrix, Martin Booij, Yvonne H. Frentzen
Life of this patent
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Abstract
One or more polyamides can be depolymerized in the presence of at least one nitrogen-containing compound. The depolymerization takes place at a pressure between about 0.5 and about 5 atm. The polyamide may be in the form of carpet waste or other heterogeneous form. Advantages include better selectivity towards the polyamide monomeric components and use of low pressure equipment to effect depolymerization.
Claims20
A process comprising the step of heating at least one polyamide comprising nylon 6 in the presence of ammonia, an amine, or a mixture thereof at a temperature between about 200.degree. C. and about 400.degree. C. and at a pressure between about 0.5 atm and about 5 atm to effect at least partial depolymerization of said polyamide and yield monomeric components of said polyamide.
A process comprising the step of heating at least one polyamide comprising nylon 6 in the presence of ammonia, an amine, or a mixture thereof at a temperature between about 200.degree. C. and about 400.degree. C. and at a pressure between 0.5 and 5 atm to effect at least partial depolymerization of said polyamide to yield monomeric components of said polyamide at selectivity greater than about 60%.
A process comprising the step of continuously depolymerizing at least one polyamide comprising nylon 6 in a reaction zone in the presence of ammonia, an amine, or a mixture thereof under substantially steady-state conditions to generate (i) at least some partially depolymerized polyamide in said reaction zone, and (ii) polyamide monomeric components in said reaction zone,
- wherein said polyamide and said ammonia, amine, or mixture thereof are continuously fed to said reaction zone, and said polyamide monomeric components are substantially and continuously removed from said reaction zone to achieve said substantial steady-state, the selectivity for said monomeric components being greater than about 60%.
Dependencies are inferred from the claim text.