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US 5,668,199 AGranted
Polymer stabilizers containing both hindered amine and hydroxylamine moieties
AssigneeCiba-Geigy Corporation
InventorsJoseph Suhadolnik, Ramanathan Ravichandran, Valerio Borzatta, Graziano Vignali
Life of this patent
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Abstract
Compounds possessing both a hindered amine moiety, such as a derivative of 2,2,6,6-tetramethylpiperidine, and a hydroxylamine moiety where the N-hydroxy group is not attached to a nitrogen atom in a piperidine ring are valuable stabilizers for protecting polymer compositions against the deleterious effects of actinic light and from the adverse effects of high temperature polymer processing environments.
Claims10
A stabilized composition which comprises
- (a) a polymer subject to the deleterious effects of actinic light or of heat, and
- (b) an effective stabilizing mount of a compound of formula IV ##STR12## wherein L.sub.3, L.sub.4 and L.sub.5 are independently --NR.sub.5 OH, --OR.sub.4, --SR.sub.4 or --NR.sub.5 R.sub.6 where R.sub.4 is alkyl of 1 to 18 carbon atoms, and R.sub.5 and R6 are independently hydrogen, alkyl of 1 to 18 carbon atoms, 2,2,6,6-tetramethyl-4-piperidyl, 1,2,2,6,6-pentamethyl-4-piperidyl, tetrahydrofurfuryl, C.sub.2 -C.sub.4 -alkyl which is substituted in the 2-, 3- or 4-position by OH, by C.sub.1 -C.sub.8 -alkoxy or by di(C.sub.1 -C.sub.4 -alkyl)amino, or --NR.sub.5 R.sub.6 is pyrrolidyl, piperidyl, morpholinyl, N-methylpiperazinyl or hexahydroazepinyl, or
- L.sub.3, L.sub.4 and L.sub.5 are independently ##STR13## where R.sub.7 is hydrogen, hydroxyl, alkyl of 1 to 12 carbon atoms or ##STR14## with the proviso that at least one of L.sub.3, L.sub.4 or L.sub.5 is ##STR15## where R.sub.7 is hydroxyl;
- or is --NR.sub.5 OH;
- E is hydrogen, oxyl, hydroxyl, alkyl of 1 to 18 carbon atoms, alkenyl of 3 to 18 carbon atoms, aralkyl of 7 to 9 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, hydroxylalkyl of 2 to 6 carbon atoms, alkoxyalkyl of 2 to 20 carbon atoms, alkanoyl of 1 to 18 carbon atoms, alkoxy of 1 to 18 carbon atoms, cycloalkoxy of 5 to 12 carbon atoms, aryloxy of 6 to 10 carbon atoms, hydroxyalkoxy of 2 to 6 carbon atoms, alkoxyalkoxy of 2 to 20 carbon atoms, aralkoxy of 7 to 15 carbon atoms or bicyclo or tricycloaliphatic oxy radical of 7 to 12 carbon atoms;
- and
- R and R.sub.1 are independently alkyl of 1 to 4 carbon atoms or together R and R.sub.1 are pentamethylene.
4 more elements
Dependencies are inferred from the claim text.