Method of separating carbon dioxide from carbon dioxide containing gas and combustion apparatus having function to separate carbon dioxide from the combustion gas

A combustion apparatus comprising:

• a tubular, vertically extending housing member and separating means for dividing said housing member into an upper, fixation chamber and a lower, combustion chamber contiguous to said fixation chamber, said fixation chamber and said combustion chamber containing a fluidized bed of particles of a metal oxide;
• air feeding means provided in a bottom portion of said combustion chamber for feeding air through said housing to maintain said metal oxide particles in a fluidized state in said fixation chamber and said combustion chamber;
• fuel feeding means provided in a lower portion of said combustion chamber for feeding solid fuel particles to said combustion chamber, so that part of said solid fuel particles are combusted to provide a first combustion zone within said combustion chamber, to form a carbon dioxide-containing gas and to leave uncombusted solid fuel particles;
• heat exchanging means disposed within said combustion chamber for recovering part of the heat of said combustion of said solid fuel particles;
• temperature controlling means, operative independently of said heat exchange means and disposed within said fixation chamber, for controlling the temperature within said fixation chamber so that said carbon dioxide in said carbon dioxide-containing gas is reacted with said metal oxide particles and fixed as the corresponding metal carbonate in said fixation chamber, thereby to form a carbon dioxide-free gas in said fixation chamber;
• a gas-solid separating means connected to an upper portion of said fixation chamber for receiving a mixture containing said metal carbonate particles, said uncombusted solid fuel particles and said carbon dioxide-free gas from said fixation chamber and for separating said mixture into a solid phase containing said metal carbonate particles and said uncombusted solid fuel particles and a gas phase containing said carbon dioxide-free gas;
• a first gas outlet for venting said carbon dioxide-free gas from said combustion apparatus;
• a decomposition furnace providing a second combustion zone disposed below and connected to said gas-solid separating means to receive said solid phase therefrom;
• oxygen feeding means provided in a bottom portion of said decomposition furnace for feeding oxygen gas to said decomposition furnace and for maintaining said solid phase in a fluidized state in said decomposition furnace, so that said uncombusted solid fuel particles are combusted in said decomposition furnace with the simultaneous decomposition of said metal carbonate into said metal oxide, thereby to form a carbon dioxide-rich gas in said decomposition furnace;
• a second gas outlet provided in a top of said decomposition furnace for withdrawing said carbon dioxide-rich gas therefrom;
• and
• transport means extending between said combustion chamber and said decomposition chamber for transporting said metal oxide particles from said decomposition furnace to said combustion chamber.