Composite silicide/silicon carbide mechanical alloy
AssigneeUniversity of Florida
InventorsS. Jayashankar, Michael J. Kaufman
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AssigneeUniversity of Florida
InventorsS. Jayashankar, Michael J. Kaufman
Estimating the term…
A method of producing a composite powder by providing particles of (I) tungsten, niobium, zirconium, titanium or mixtures thereof, (II) silicon and (III) carbon in a proportion relative to each other so as to possess an overall chemical composition in that segment of the ternary diagram of FIGS. 2(a), 2(b), 2(c) and 2(d) designated A, and subjecting the particles to a mechanical alloying process under conditions and for a time sufficient to produce the composite powder. Also disclosed is a method of forming a substantially oxygen-free composition of matter comprising a matrix substance of WSi.sub.2, NbSi.sub.2, ZrSi.sub.2, TiSi.sub.2 or alloys thereof having SiC dispersed therein, the method comprising consolidating the above-described composite powder. Also disclosed is a method of forming oxidation- and wear-resistant coatings by subjecting the composite powder whose composition lies in segment A to a metallurgical process such as plasma spraying. A method of forming a composite material of uniformly dispersed particles of silicon carbide in a silicide or an alloy silicide matrix is also disclosed. The matrix contains alloy silicides such as (Mo,W)Si.sub.2. The volume fraction of the silicon carbide may be varied from 10-90%. A method is also disclosed for producing hybrid composites consisting of a third phase of fibers or whiskers dispersed among a silicide/silicon carbide two-phase microstructure derived from the composite powder.
A method for producing a substantially oxygen-free composite powder comprising WSi.sub.2 and SiC comprising providing particles of tungsten, silicon and carbon in a proportion relative to each other required to produce a composite powder of WSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(a) designated A, and subjecting said particles to mechanical alloying under conditions and for a time sufficient to produce said composite powder.
A substantially oxygen-free composite mechanical alloy powder comprising WSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(a) designated A and, optionally, a second phase admixed therewith.
A method for producing a substantially oxygen-free composite powder comprising NbSi.sub.2 and SiC comprising providing particles of niobium, silicon and carbon in a proportion relative to each other required to produce a composite powder of NbSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(b) designated A, and subjecting said particles to mechanical alloying under conditions and for a time sufficient to produce said composite powder.
A substantially oxygen-free composite mechanical alloy powder comprising NbSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(b) designated A and, optionally, a second phase admixed therewith.
A method for producing a substantially oxygen-free composite powder comprising ZrSi.sub.2 and SiC comprising providing particles of zirconium, silicon and carbon in a proportion relative to each other required to produce a composite powder of ZrSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(c) designated A, and subjecting said particles to mechanical alloying under conditions and for a time sufficient to produce said composite powder.
A substantially oxygen-free composite mechanical alloy powder comprising ZrSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(c) designated A and, optionally, a second phase admixed therewith.
A method for producing a substantially oxygen-free composite powder comprising TiSi.sub.2 and SiC comprising providing particles of titanium, silicon and carbon in a proportion relative to each other required to produce a composite powder of TiSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(d) designated A, and subjecting said particles to mechanical alloying under conditions and for a time sufficient to produce said composite powder.
A substantially oxygen-free composite mechanical alloy powder comprising TiSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(d) designated A and, optionally, a second phase admixed therewith.
A method for producing a substantially oxygen-free composite powder comprising WSi.sub.2, MoSi.sub.2 and SiC comprising providing particles of tungsten, molybdenum, silicon and carbon in a proportion relative to each other required to produce a composite powder of WSi.sub.2, MoSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(a) designated A wherein W represents tungsten and molybdenum, and subjecting said particles to mechanical alloying under conditions and for a time sufficient to produce said composite powder.
A substantially oxygen-free composite mechanical alloy powder comprising WSi.sub.2, MoSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 2(a) designated A wherein W represents tungsten and molybdenum and, optionally, said powder additionally containing a second phase.
A substantially oxygen-free composite mechanical alloy powder comprising MoSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 1 designated A and admixed therewith a second phase.
Dependencies are inferred from the claim text.