Hydrogen producing apparatus

A hydrogen producing apparatus in which hydrogen produced from a steam reforming reaction in a fixed bed catalyst is separated and collected by passing through a partitioning wall having selective permeability for hydrogen, said apparatus comprising:

• an outer tubular cylinder having a closed end wall at one end thereof;
• an intermediate tubular cylinder in said outer cylinder in coaxial spaced relationship thereto to form an outer annulus therebetween;
• an inner tubular cylinder in said intermediate cylinder in coaxial spaced relationship therewith to form an inner annulus therebetween and having an inner hollow chamber;
• heating means disposed substantially in said inner hollow chamber in said inner cylinder for producing a temperature in said hollow chamber and inner annulus sufficiently high to convert process gas in said inner annulus in the the presence of a reforming catalyst into hydrogen, said intermediate and inner cylinders being joined together at one end of each in spaced relationship to said closed end wall of said outer cylinder to form a closed end portion of said inner annulus, and so that said outer annulus is in communication with said inner hollow chamber in said inner cylinder;
• a catalyst layer of reforming catalyst in said inner annulus;
• at least one hydrogen-permeable tube having hydrogen permeability disposed in said catalyst layer in said inner annulus and having a closed end proximate said closed end portion of said inner annulus and an outlet end;
• a source of process feed gas;
• process feed gas inlet means for conducting process feed gas from said source thereof to said inner annulus, said process feed gas means comprising means for introducing said process feed gas adjacent said closed end portion of said inner annulus so that said process feed gas flows upwardly in said reforming catalyst layer;
• and
• process feed gas outlet means communicating with said inner annulus for discharging said feed gas after separation of hydrogen therefrom;
• and
• a suction pump having an inlet connectable to said outlet end of said at least one hydrogen-permeable tube;
• so that said heating means produces said high temperature in said hollow chamber and said inner annulus, process gas introduced into said inner annulus flows through said catalyst layer and is converted into hydrogen at said high temperature, and said hydrogen permeates said at least one hydrogen-permeable tube and is selectively separated thereby and is conducted out of said apparatus through said outlet end of said at least one hydrogen-permeable tube by said suction pump.

A hydrogen producing apparatus in which hydrogen produced from a steam reforming reaction in a fixed bed catalyst is separated and collected by passing through a partitioning wall having selective permeability for hydrogen, said apparatus comprising:

• an upright outer tubular cylinder having a closed bottom end wall;
• an upright intermediate tubular cylinder in said outer cylinder in coaxial spaced relationship therewith to form an outer annulus therebetween;
• an upright inner tubular cylinder in said intermediate cylinder in coaxial spaced relationship therewith to form an inner annulus therebetween and having an inner hollow chamber, an upper end portion of said inner hollow chamber and a ceiling wall in said upper end portion;
• a drooping combustion burner heating means on said ceiling wall for producing a temperature in said hollow chamber and inner annulus sufficiently high to convert process gas in said inner annulus in the presence of a reforming catalyst into hydrogen;
• means for joining said intermediate and inner cylinders together at the lower ends thereof in spaced relationship to said closed end wall of said outer cylinder to form a closed lower end portion of said inner annulus, and so that said outer annulus is in communication with said inner hollow chamber in said inner cylinder;
• a catalyst layer of reforming catalyst in said inner annulus;
• a double-walled hydrogen-permeable cylinder in said catalyst in said inner annulus in coaxial spaced relationship with said intermediate and inner cylinders and comprising coaxial spaced outer and inner walls and an annular bottom wall connected to said outer and inner walls to form a further annulus therebetween closed at the lower end thereof, said walls comprising an outer hydrogen-permeable metal membrane on an inorganic porous layer;
• an outlet end for said hydrogen-permeable cylinder communicating with said further annulus therein;
• a source of process feed gas;
• process feed gas inlet means for conducting process feed gas from said source thereof to said inner annulus;
• process feed gas outlet means communicating with said inner annulus for discharging said feed gas after separation of hydrogen therefrom;
• and
• a source of sweep gas;
• and
• at least one sweep gas tube disposed within said further annulus in said double-walled hydrogen-permeable cylinder and having an inlet end connectable to said source of sweep gas and an outlet end proximate said annular bottom wall of said hydrogen-permeable cylinder;
• so that said heating means produces said high temperature in said hollow chamber and said inner annulus, process gas introduced into said inner annulus flows through said catalyst layer and is converted into hydrogen at said high temperature, and said hydrogen permeates said double-walled hydrogen-permeable cylinder and is selectively separated thereby and flows with said sweep gas through said further annulus and out of said apparatus through said outlet end of said hydrogen-permeable cylinder.

A hydrogen producing apparatus in which hydrogen produced from a steam reforming reaction in a fixed bed catalyst is separated and collected by passing through a partitioning wall having selective permeability for hydrogen, said apparatus comprising:

• an upright outer tubular cylinder having a closed bottom end wall;
• an upright intermediate tubular cylinder in said outer cylinder in coaxial spaced relationship therewith to form an outer annulus therebetween;
• an upright inner tubular cylinder in said intermediate cylinder in coaxial spaced relationship therewith to form an inner annulus therebetween and having an inner hollow chamber, an upper end portion of said inner hollow chamber and a ceiling wall in said upper end portion;
• a drooping combustion burner heating means on said ceiling wall for producing a temperature in said hollow chamber and inner annulus sufficiently high to convert process gas in said inner annulus in the presence of a reforming catalyst into hydrogen;
• means for joining said intermediate and inner cylinders together at the lower ends thereof in spaced relationship to said closed end wall of said outer cylinder to form a closed lower end portion of said inner annulus, and so that said outer annulus is in communication with said inner hollow chamber in said inner cylinder;
• a reforming catalyst in said inner annulus;
• a double-walled hydrogen-permeable cylinder in said inner annulus in coaxial spaced relationship with said intermediate and inner cylinders and comprising coaxial spaced outer and inner walls and an annular bottom wall connected to said outer and inner walls to form a further annulus therebetween closed at the lower end thereof, said walls comprising an outer hydrogen-permeable metal membrane on an inorganic porous layer;
• an inner catalyst layer of reforming catalyst between said inner wall and said inner cylinder;
• an outer catalyst layer of reforming catalyst between said outer wall and said outer cylinder, and communicating with said inner catalyst layer in said closed lower end portion of said inner annulus;
• a source of sweep gas;
• an upper open end for said hydrogen-permeable cylinder communicating with said source of sweep gas;
• a source of process feed gas;
• process feed gas inlet means for conducting process feed gas from said source thereof to said inner catalyst layer;
• process feed gas outlet means communicating with said inner annulus for discharging said feed gas after separation of hydrogen therefrom;
• at least one sweep gas tube disposed within said further annulus in said double-walled hydrogen-permeable cylinder and having a lower open end proximate said annular bottom wall of said hydrogen-permeable cylinder and an upper outlet end;
• an annular pipe header proximate said annular bottom wall in said further annulus and connected to said lower open end of said at least one sweep gas tube;
• and
• a plurality of inlet holes in said pipe header;
• so that said heating means produces said high temperature in said hollow chamber and said inner annulus, process feed gas introduced into said inner catalyst layer flows downwardly through said inner catalyst layer and upwardly through said outer catalyst layer and is converted into hydrogen at said high temperature, and said hydrogen permeates said double-walled hydrogen-permeable cylinder and is selectively separated thereby and flows with said sweep gas through said further annulus, through said inlet holes in said pipe header, through said pipe header and sweep gas tube and out of said apparatus through said upper outlet end of said sweep gas tube.

A hydrogen producing apparatus in which hydrogen produced from a steam reforming reaction in a fixed bed catalyst is separated and collected by passing through a partitioning wall having selective permeability for hydrogen, said apparatus comprising:

• an upright outer tubular cylinder having a closed bottom end wall;
• an upright intermediate tubular cylinder in said outer cylinder in coaxial spaced relationship therewith to form an outer annulus therebetween;
• an upright inner tubular cylinder in said intermediate cylinder in coaxial spaced relationship therewith to form an inner annulus therebetween and having an inner hollow chamber, an upper end portion of said inner hollow chamber and a ceiling wall in said upper end portion;
• a drooping combustion burner heating means on said ceiling wall for producing a temperature in said hollow chamber and inner annulus sufficiently high to convert process gas in said inner annulus in the presence of a reforming catalyst into hydrogen;
• means for joining said intermediate and inner cylinders together at the lower ends thereof in spaced relationship to said closed end wall of said outer cylinder to form a closed lower end portion of said inner annulus, and so that said outer annulus is in communication with said inner hollow chamber in said inner cylinder;
• a catalyst layer of reforming catalyst in said inner annulus;
• a double-walled hydrogen-permeable cylinder in said catalyst in said inner annulus in coaxial spaced relationship with said intermediate and inner cylinders and comprising coaxial spaced outer and inner walls and an annular bottom wall connected to said outer and inner walls to form a further annulus therebetween closed at the lower end thereof, each of said walls comprising an outer hydrogen-permeable metal membrane on an inorganic porous layer;
• an outlet end for said hydrogen-permeable cylinder communicating with said further annulus therein;
• a source of process feed gas;
• process feed gas inlet means for conducting process feed gas from said source thereof to said inner annulus;
• process feed gas outlet means communicating with said inner annulus for discharging said feed gas after separation of hydrogen therefrom;
• and
• a source of sweep gas;
• and
• a cylindrical partitioning wall disposed within said further annulus in said double-walled hydrogen-permeable cylinder and having a lower end in adjacent spaced relationship to said annular bottom wall of said hydrogen-permeable cylinder, said partitioning wall dividing said inner annulus into two coaxial annular sweep gas flow channels;
• so that said heating means produces said high temperature in said hollow chamber and said inner annulus, process gas introduced into said inner annulus flows through said catalyst layer and is converted into hydrogen at said high temperature, and said hydrogen permeates said double-walled hydrogen-permeable cylinder and is selectively separated thereby and flows with said sweep gas through said two flow channels and out of said apparatus through said outlet end of said hydrogen-permeable cylinder.

A hydrogen producing apparatus in which hydrogen produced from a steam reforming reaction in a fixed bed catalyst is separated and collected by passing through a partitioning wall having selective permeability for hydrogen, said apparatus comprising:

• an upright outer tubular cylinder having a closed bottom end wall;
• an upright intermediate tubular cylinder in said outer cylinder in coaxial spaced relationship therewith to form an outer annulus therebetween;
• an upright inner tubular cylinder in said intermediate cylinder in coaxial spaced relationship therewith to form an inner annulus therebetween and having an inner hollow chamber, an upper end portion of said inner hollow chamber and a ceiling wall in said upper end portion;
• a drooping combustion burner heating means on said ceiling wall for producing a temperature in said hollow chamber and inner annulus sufficiently high to convert process gas in said inner annulus in the presence of a reforming catalyst into hydrogen;
• means for joining said intermediate and inner cylinders together at the lower ends thereof in spaced relationship to said closed end wall of said outer cylinder to form a closed lower end portion of said inner annulus, and so that said outer annulus is in communication with said inner hollow chamber in said inner cylinder;
• a catalyst layer of reforming catalyst in said inner annulus;
• a double-walled hydrogen-permeable cylinder in said catalyst in said inner annulus in coaxial spaced relationship with said intermediate and inner cylinders and comprising coaxial spaced outer and inner walls and an annular bottom wall connected to said outer and inner walls to form a further annulus therebetween closed at the lower end thereof, said walls comprising an outer hydrogen-permeable metal membrane on an inorganic porous layer;
• an outlet end for said hydrogen-permeable cylinder communicating with said further annulus therein;
• a source of process feed gas;
• process feed gas inlet means connected to said inner annulus for conducting process feed gas from said source thereof to said inner annulus;
• and
• process feed gas outlet means communicating with said inner annulus for discharging said feed gas after separation of hydrogen therefrom;
• and
• suction pump means operatively connected to said outlet end of said double-walled hydrogen-permeable cylinder for drawing hydrogen from said further annulus;
• so that said heating means produces said high temperature in said hollow chamber and said inner annulus, process feed gas introduced into said inner annulus flows through said catalyst layer and is converted into hydrogen at said high temperature, and said hydrogen permeates said double-walled hydrogen-permeable cylinder and is selectively separated thereby and flows through said further annulus and out of said apparatus through said outlet end of said hydrogen-permeable cylinder and said suction pump.

A hydrogen producing apparatus in which hydrogen produced from a steam reforming reaction in a fixed bed catalyst is separated and collected by passing through a partitioning wall having selective permeability for hydrogen, said apparatus comprising:

• an upright outer tubular cylinder having a closed end wall at one end thereof;
• an upright intermediate tubular cylinder in said outer cylinder in coaxial spaced relationship thereto to form an outer annulus therebetween;
• an upright inner tubular cylinder in said intermediate cylinder in coaxial spaced relationship therewith to form an inner annulus therebetween and having an inner hollow chamber and an upper end;
• a ceiling wall on said upper end of said inner cylinder;
• drooping combustion burner heating means located on said ceiling wall so that said burner is directed downwardly into said inner hollow chamber in said inner cylinder for producing a temperature in said hollow chamber and inner annulus sufficiently high to convert process gas in said inner annulus in the presence of a reforming catalyst into hydrogen, said intermediate and inner cylinders being joined together at one end of each in spaced relationship to said closed end wall of said outer cylinder to form a closed end portion of said inner annulus, and so that said outer annulus is in communication with said inner hollow chamber in said inner cylinder;
• a catalyst layer of reforming catalyst in said inner annulus;
• a plurality of hydrogen-permeable tubes having hydrogen permeability disposed in said catalyst layer in said inner annulus in substantially circular spaced relationship, each hydrogen-permeable tube having a closed end adjacent said closed end portion of said inner annulus and comprising an outer hydrogen-permeable metal membrane having an inner wall, and an inorganic porous layer on said inner wall of said metal membrane;
• a source of process feed gas;
• process feed gas inlet means for conducting process feed gas from said source thereof to said inner annulus;
• process feed gas outlet means communicating with said inner annulus for discharging said feed gas after separation of hydrogen therefrom;
• a cylindrical partitioning wall in said inner annulus in radial spaced relationship to and between said hydrogen-permeable tubes and said intermediate cylinder and having a lower end in adjacent spaced relationship to said closed end portion of said inner annulus and an upper end defining with an upper portion of said intermediate cylinder said process feed gas inlet means, said catalyst layer being disposed between said partitioning wall and said hydrogen-permeable tubes;
• and
• suction pump means operatively connected to said hydrogen-permeable tubes for withdrawing separated hydrogen therefrom;
• so that said heating means produces said high temperature in said hollow chamber and said inner annulus, process feed gas introduced into said inner annulus through said inlet means therefor flows through said space between said intermediate cylinder and said partitioning wall, through said space between said lower end of said partitioning wall, through said closed end portion of said inner annulus and through said catalyst layer, said hydrogen permeates said hydrogen-permeable tubes and is selectively separated thereby and flows through said hydrogen-permeable tubes and out of said apparatus through said suction pump means.

A hydrogen producing apparatus in which hydrogen produced from a steam reforming reaction in a fixed bed catalyst is separated and collected by passing through a partitioning wall having selective permeability for hydrogen, said apparatus comprising:

• an upright outer tubular cylinder having a closed end wall at one end thereof;
• an upright intermediate tubular cylinder in said outer cylinder in coaxial spaced relationship thereto to form an outer annulus therebetween;
• an upright inner tubular cylinder in said intermediate cylinder in coaxial spaced relationship therewith to form an inner annulus therebetween and having an inner hollow chamber and an upper end;
• a ceiling wall on said upper end of said inner cylinder;
• drooping combustion burner heating means located on said ceiling wall so that said burner is directed downwardly into said inner hollow chamber in said inner cylinder for producing a temperature in said hollow chamber and inner annulus sufficiently high to convert process gas in said inner annulus in the presence of a reforming catalyst into hydrogen, said intermediate and inner cylinders being joined together at one end of each in spaced relationship to said closed end wall of said outer cylinder to form a closed end portion of said inner annulus, and so that said outer annulus is in communication with said inner hollow chamber in said inner cylinder;
• a catalyst layer of reforming catalyst in said inner annulus;
• a plurality of hydrogen-permeable tubes having hydrogen permeability disposed in said catalyst layer in said inner annulus in substantially circular spaced relationship, each hydrogen-permeable tube having a closed end adjacent said closed end portion of said inner annulus and comprising an outer hydrogen-permeable metal membrane having an inner wall, and an inorganic porous layer on said inner wall of said metal membrane;
• a source of process feed gas;
• process feed gas inlet means for conducting process feed gas from said source thereof to said inner annulus;
• process feed gas outlet means communicating with said inner annulus for discharging said feed gas after separation of hydrogen therefrom;
• a cylindrical partitioning wall in said inner annulus in radial spaced relationship to and between said hydrogen-permeable tubes and said inner cylinder and having a lower end in adjacent spaced relationship to said closed end portion of said inner annulus and an upper end defining with an upper portion of said inner cylinder said process feed gas inlet means;
• and
• suction pump means operatively connected to said hydrogen-permeable tubes for withdrawing separated hydrogen therefrom;
• so that said heating means produces said high temperature in said hollow chamber and said inner annulus, process feed gas introduced into said inner annulus through said inlet means therefor flows through said space between said inner cylinder and said partitioning wall, through said space between said lower end of said partitioning wall, through said closed end portion of said inner annulus and through said catalyst layer, said hydrogen permeates said hydrogen-permeable tubes and is selectively separated thereby and flows through said hydrogen-permeable tubes and out of said apparatus through said suction pump means.