Process for the production of polyurethane lens
AssigneeHoya Corporation
InventorsMasahisa Kosaka, Yukio Kageyama
Life of this patent
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Abstract
The present invention relates to a process for the production of a polyurethane lens, which comprises the step (a) of providing a polyisocyanate compound and two or more polythiol compounds which have different reaction rates with the polyisocyanate compound and adding an alkyltin halide compound to the above polyisocyanate compound, and, after the step (a), the step (b) of mixing the polyisocyanate compound and the two or more polythiol compounds together with the alkyltin halide compound of the general formula (I) to allow them to react, and obtaining a polyurethane lens.
Claims15
A process for producing of a polyurethane lens comprising the steps of:
- (A) selecting two polythiol compounds which have different reaction rates with a polyisocyanate compound by:
- (i) mixing a first candidate polythiol compound with m-xylylene diisocyanate, as a standard polyisocyanate compound, in an --NCO group/--SH group mixing ratio of 1.0, measuring the viscosity of the resultant mixture at 20 .degree. C. immediately after mixing and again 2 hours after preparation of the mixture, and determining a change in viscosity between the first and second measurements,
- (ii) mixing a second candidate polyisocyanate compound with m-xylylene diisocyanate and measuring viscosity change in the same manner as in the above step (i),
- (iii) repeating step (ii) for additional candidate polythiol compounds, and
- (iv) comparing the amount of viscosity change for any two polythiol compounds so measured, and when a difference between the viscosity change is at least 100 cps, selecting these two candidate polythiol compounds which have different reaction rates with the standard polyisocyanate compound;
- (B) adding two or more of the polythiol compounds selected in step (A) to a mixture of polyisocyanate compound and an alkyltin halide compound of the formula (I),
- (R.sub.1).sub.c --Sn--X.sub.4 --c (I)
- wherein R.sub.1 is methyl, ethyl, propyl or butyl, X is a fluorine atom, a chlorine atom or a bromine atom and c is an integer of 1 to 3, allowing them to react, and thereafter
- (C) obtaining a polyurethane lens.
The process of clam 1, wherein the polyisocyanate compound and the polythiol compounds are used in an (--NCO group)/(--SH group) molar ratio of 0.9 to 1.2.
Dependencies are inferred from the claim text.