A black-and-white photothermographic element comprising a support bearing at least one photosensitive, image-forming, photothermographic emulsion layer comprising:
- (a) a photosensitive silver halide;
- (b) a non-photosensitive, reducible silver source;
- (c) a reducing agent system for silver ion;
- and
- (d) a binder.
- wherein the reducing agent system comprises:
- (i) at least one hindered phenol;
- and
- (ii) at least one compound of the formula ##STR9## wherein:
- R represents an aryl group or an electron withdrawing group;
- and
- HET represents a 5- or 6-membered heteroaromatic ring group attached through a non-quaternary ring nitrogen atom of said 5- or 6-membered ring, the heteroaromatic ring being composed of only carbon and nitrogen atoms, with up to 4 nitrogen atoms.