Polymers based on polyarylene siloxanes and freeradical-polymerizable monomers
AssigneeHoechst Aktiengesellschaft
InventorsHorst-Tore Land, Walter Schubert, Reinhardt Kalus
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AssigneeHoechst Aktiengesellschaft
InventorsHorst-Tore Land, Walter Schubert, Reinhardt Kalus
Estimating the term…
Polymers can be obtained by free-radical polymerization of monomers in the presence of a dissolved polysiloxane. The free-radical-polymerizable monomers used are at least one compound of the formula I ##STR1## where R.sup.1 and R.sup.2 are, independently of one another, hydrogen, COOH, C.sub.1 -C.sub.18 -alkyl, cyclohexyl, C.sub.1 -C.sub.4 -alkyl-cyclohexyl, C.sub.6 -C.sub.10 -bicycloalkyl, C.sub.6 -C.sub.18 -tricycloalkyl, R.sup.3 is hydrogen or methyl, R.sup.4 is hydrogen, (C.sub.1 -C.sub.20)-alkyl, 2-hydroxypropyl, glycidyl, --[CH.sub.2 CH.sub.2 --O].sub.n H, having n=1 to 5, --[CH.sub.2 ].sub.m --OH, having m=3 to 18, in particular m=3 to 8, --[CH.sub.2 ].sub.2 O--[CO--(CH.sub.2).sub.5 ].sub.x OH, where x=a number from 1 to 3, or --[CH.sub.2 CHOHCH.sub.2 ]--O--(CO)R, where R is a C.sub.1 to C.sub.18 -alkyl radical. The polysiloxane used is at least one aromatic polyarylene siloxane of the formula III ##STR2## where R.sup.9 and R.sup.10 are, independently of one another, a C.sub.1 -C.sub.12 -alkyl radical, a C.sub.6 -C.sub.14 -aryl radical, or an unsubstituted or substituted vinyl radical, and R.sup.11, R.sup.12, R.sup.13 and R.sup.14 are, independently of one another, hydrogen, a C.sub.1 -C.sub.3 -alkyl radical or a substituted or unsubstituted C.sub.6 -C.sub.14 -aryl radical and --X-- is a group --C(CH.sub.3).sub.2 --, --C(CF.sub.3).sub.2 --, --S--, --SO.sub.2 --, --CH.sub.2 -- or a cyclohexylidene group, or a single chemical bond and M is equal to 0 or 1 and N is a number from 2 to 500, in particular from 3 to 200.
A polymer obtained by free-radical polymerization of free-radical-polymerizable monomers in the presence of a polysiloxane dissolved in a solvent, where the free-radical-polymerizable monomers used are at least one compound of the formula I, ##STR7## where R.sup.1 and R.sup.2 are, independently of one another, hydrogen, COOH, C.sub.1 -C.sub.18 -alkyl, cyclohexyl, C.sub.1 -C.sub.4 -alkylcyclohexyl, C.sub.6 -C.sub.10 -bicycloalkyl, or C.sub.6 -C.sub.18 -tricycloalkyl,
Dependencies are inferred from the claim text.
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On to polysiloxanes: on to polysiloxanes having carbon-to-carbon double bonds
Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G: on to polysiloxanes
Polymers provided for in subclass C08G: polysiloxanes
Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Term ended 26 Apr 2015 (estimated)
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The present invention relates to polymers based on polyarylene siloxanes and on free-radical-polymerizable monomers, a process for their preparation and their use.
Polymers which are prepared with the aid of free-radical-forming initiators by polymerization of organic monomers containing a C--C double bond have, owing to their properties matched to the respective application, found extremely wide use.
Polysiloxane compounds are also technologically important, with the aliphatic poly(dimethylsiloxanes) representing the most important class of materials (J. J. Lebrun, H. Porte in: "Comprehensive Polymer Science", Volume 5, Chapter 35: "Polysiloxanes", pp. 593-609, Pergamon Press New York, 1989).
The following examples illustrate the invention.
All parts are by weight.
A 4 liter three-neck flask fitted with stirrer, dropping funnel and reflux condenser is initially charged with 220 parts of the .alpha.,.omega.-hydroxy-functional polyarylene siloxane of the formula IV ##STR6## and 170.5 parts of butyl acetate (=BuAc) and the mixture is heated to boiling. Subsequently, a mixture of