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US 5,633,320 AGranted
Thermoplastic polyester resin composition
AssigneeMitsui Petrochemical Industries, Ltd.
InventorsYasuo Tanaka, Yohji Hayakawa
Life of this patent
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Abstract
There is provided a thermoplastic polyester resin composition comprising a thermoplastic polyester resin (A) and a graft modified product (B) of a mixture of two different specific ethylene.1-butene random copolymers in a weight ratio of 95/5 to 50/50. A molded article having excellent impact resistance at low temperatures and mechanical strength can be obtained from this composition.
Claims9
A thermoplastic polyester resin composition comprising a thermoplastic polyester resin (A) and a graft modified mixture of ethylene.1-butene copolymers (B) in a weight ratio of 95/5 to 50/50, wherein
- (1) the graft modified mixture (B) is essentially composed of
- (i) an ethylene.1-butene random copolymer (C) which contains units derived from 1-butene in an amount of 5 to 15 mol % and has an intrinsic viscosity [.eta.], measured at 135.degree. C. in a decalin solvent, of 0.5 to 3.5 dl/g, a glass transition temperature (Tg), measured by a DSC method, of -50.degree. C. or less and a crystallinity, measured by an X-ray diffraction method, of less than 40%,
- (ii) an ethylene.1-butene random copolymer (D) which contains units derived from 1-butene in an amount of 16 to 25 mol % and has an intrinsic viscosity [.eta.], measured at 135.degree. C. in a decalin solvent, of 0.5 to 3.5 dl/g, a glass transition temperature (Tg), measured by a DSC method, of -50.degree. C. or less and a crystallinity, measured by an X-ray diffraction method, of less than 15%, and
- (iii) graft units derived from at least one monomer selected from unsaturated carboxylic acids and derivatives thereof and bonded to at least one of the two copolymers, and
- (iv) the graft modified mixture (B) contains units derived from 1-butene in an amount of 11 to 19 mol % based on the total of units derived from ethylene and 1-butene and has an intrinsic viscosity [.eta.], measured by the above method, of 0.5 to 3.5 dl/g, a glass transition temperature, measured by the above method, of -50.degree. C. or less, and a crystallinity, measured by the above method, of less than 10%,
- (2) the amount of the above graft units is 0.01 to 10% by weight based on the total amount of the copolymer (C) and the copolymer (D), and
- (3) the weight ratio ((C)/(D)) of the copolymer (C) to the copolymer (D) is 10/90 to 95/5.
4 more elements
Dependencies are inferred from the claim text.