Azodyes containing a bridge member based on diamino-substituted triazines
AssigneeCiba-Geigy Corporation
InventorUrs Lauk
Life of this patent
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Abstract
Dye mixtures which comprise at least one anionic acid dye of the formula ##STR1## together with at least one anionic acid dye of the formula ##STR2## in which the substituents are as defined in claim 1, and the novel dyes of the formulae (1) and (2) are direct dyes for cellulosic fibre materials in particular. They have a high heat stability and are particularly suitable for one-bath, one-stage dyeing of polyester/cotton blend fabrics with a disperse dye for the polyester fibres under the dyeing conditions for polyester fibres.
Claims8
An anionic acid dye of the formula ##STR186## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or C.sub.1 -C.sub.4 alkyl,
- B.sub.1 is an aliphatic or aromatic bridge member,
- A.sub.1 and A.sub.2 independently of one another are the radical of a monoazo- or disazo dye or the radical of a metal complex azo dye,
- n is the number 0 or 1 and
- Y.sub.1 and Y.sub.2 independently of one another are a radical of the formula ##STR187## in which R.sub.7, R.sub.8 and R.sub.8 ' independently of one another are hydrogen or C.sub.1 -C.sub.8 alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 alkoxy, halogen, amino or sulfato, and
- E.sub.1 is C.sub.2 -C.sub.8 alkylene which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 alkoxy, halogen, amino or sulfato and is uninterrupted or interrupted by one or more groups -O-, or C.sub.5 -C.sub.7 cycloalkylene, C.sub.5 -C.sub.7 cycloalkylene-C.sub.1 -C.sub.8 alkylene or C.sub.1 -C.sub.8 alkylene-C.sub.5 -C.sub.7 cycloalkylene, each of which is unsubstituted or substituted in the alkylene radical by hydroxyl or C.sub.1 -C.sub.4 alkoxy and in the cycloalkyl ring by C.sub.1 -C.sub.4 alkyl, and in which dye of formula (1) the number of sulfo groups is greater than the number of cationic groups and basic groups.
Dependencies are inferred from the claim text.