Zirconium/cerium mixed oxide catalyst/catalyst support compositions having high/stable specific surfaces
AssigneeRhone-Poulenc Chimie
InventorsThierry Chopin, Gabriel Vilmin
Life of this patent
Estimating the term…
Loading patent…
AssigneeRhone-Poulenc Chimie
InventorsThierry Chopin, Gabriel Vilmin
Estimating the term…
Zirconium/cerium mixed oxides (optionally including thermally stabilizing dopant values), comprising solid solutions thereof, having contents of zirconium of up to 99% by weight, and having high specific surface areas, are well suited as catalysts and/or catalyst supports, notably for the treatment/conversion of vehicular exhaust gases; such ZrO.sub.2 /CeO.sub.2 mixed oxides are conveniently prepared by (i) intimately admixing a zirconium sol with a cerium sol, the ratio r of the mean diameter r.sub.l of the particles of the zirconium sol to the diameter r.sub.2 of the particles of the cerium sol being at least 5, (ii) adding a precipitating amount of a base thereto, (iii) recovering the precipitate thus formed, and (iv) calcining the recovered precipitate.
In a process for the catalytic conversion of exhaust gases emanating from an internal combustion engine, the improvement which comprises, as the catalyst/catalyst support therefor, a zirconium/cerium mixed oxide having a specific surface area of greater than 10 m.sup.2 /g.
Dependencies are inferred from the claim text.