Process for the production of conductive and magnetic transitin metal oxide coated three dimensional substrates
AssigneeEnsci, Inc.
InventorsThomas J. Clough, Victor L. Grosvenor, Naum Pinsky
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Abstract
Processes for coating substrates, in particular substrates including shielded surfaces, with transition metal oxide-containing coatings are disclosed. Such processes comprise contacting a substrate with a transition metal oxide precursor, preferably maintaining the precursor coated substrate at conditions to equilibrate the coating, and then oxidizing the precursor to form a substrate containing transition metal oxide. Also disclosed are substrates coated with transition metal oxide-containing coatings for use in various applications.
Claims20
A process for producing at least one or both of an electrically conductive or magnetic coated inorganic three dimensional substrate comprising:
- Contacting an inorganic three dimensional substrate which includes external surfaces and shielded surfaces which are at least partially shielded by other portions of said substrate with a composition comprising a transition metal oxide forming compound having a melting point of from about 100.degree. C. to about 650.degree. C. and an atomic number of from 21-to-31, 39-to-49 and 71-to-81 inclusive at conditions effective to form a transition metal oxide forming compound containing coating on at least a portion of said three dimensional substrate;
- including at least a portion of shielded surfaces of said substrate;
- forming a liquidous coating from said transition metal oxide forming compound on at least a portion of three dimensions of said substrate including the shielded surfaces of said substrate under substantially non deleterious oxidizing and/or hydrolyzing conditions effective to do at least one of the following:
- (1) coat a larger portion of said substrate with the said transition metal oxide forming compound coating;
- (2) distribute said transition metal oxide forming compound coating over said substrate;
- and (3) make transition metal oxide forming compound coating more uniform in thickness,
- contacting said substrate having said liquidous transition metal oxide forming compound coating thereon with an oxidizing agent at conditions effective to convert the transition metal oxide forming compound to a transition metal oxide and form a transition metal oxide coated substrate including the shielded surfaces and recovering at least one or both of an electrically conductive or magnetic transition metal oxide coated three dimensional substrate.
A process for coating surfaces of an inorganic three dimensional substrate with at least one or both of an electrically conductive or magnetic transition metal oxide coating which comprises:
- contacting an inorganic three dimensional substrate with a composition comprising a transition metal oxide precursor powder having an atomic number of from 21-to-31, 39-to-49 and 71-to-81 inclusive at conditions effective to form a coating containing transition metal oxide precursor on at least a portion of the substrate;
- forming a liquidous coating from said transition metal oxide precursor on at least a portion of the three dimensions of said substrate including the shielded surfaces of said substrate and at conditions effective to do at least one of the following:
- (1) coat a larger portion of said substrate with said coating;
- (2) distribute said coating over said substrate;
- and (3) make said coating more uniform in thickness and contacting said liquidous coated substrate with an oxidizing agent at conditions effective to convert the coating to a transition metal oxide and form a transition metal oxide on at least a portion of said three dimensions of said substrate including the shielded surface and recovering at least one or both of an electrically conductive or magnetic transition metal oxide coated three dimensional substrate.
Dependencies are inferred from the claim text.