Process for preparing zeolite Y with increased mesopore volume
AssigneePQ Corporation
InventorsDavid A. Cooper, Thomas W. Hastings, Elliot P. Hertzenberg
Life of this patent
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Abstract
The mesopore volume in pores of diameters ranging from 2 to 60 nm of zeolite Y materials is increased by the hydrothermal treatment of such zeolites at temperatures above the atmospheric boiling point of the treating solution. Unique zeolites are produced as result of such process.
Claims21
A stabilized zeolite having the structure of zeolite Y and mesopore volume contained in mesopores of about 2 nm to about 60 nm in diameter wherein the relationship between the SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio ("SAR"), the unit cell constant, a.sub.0, and mesopore volume is defined by the following table:
- ______________________________________ SiO.sub.2 /AlO.sub.3 Zeolite Molar Unit Cell Mesopore Type Ratio Constant(.ANG.) Volume (cc/g) ______________________________________ USY 5-10 24.6 .gtoreq. a.sub.o .gtoreq. 24.5 0.202 or greater VUSY 5-15 24.5 >
- a.sub.o .gtoreq. 24.3 0.313 or greater. ______________________________________
A process for increasing the mesopore volume contained in mesopores having diameters of about 2 nm to about 60 nm of a stabilized zeolite having the structure of zeolite Y to produce a zeolite having the structure of zeolite Y and mesopore volume contained in mesopores of about 2 nm to about 60 nm in diameter, said process comprising:
- contacting hydrothermally said stabilized zeolite with an aqueous solution, having dissolved therein one or more salts, acids, bases, and/or water-soluble organic compounds, such contacting being made at a temperature above the atmospheric boiling point of the solution for a period of time from about 2 hours or more thereby producing a stabilized zeolite having the structure of zeolite Y and a mesopore volume contained in mesopores of about 2 nm to about 60 nm in diameter in the product zeolite of at least 5 percent greater than the mesopore volume of the zeolite prior to said contact, then separating, washing and recovering the product zeolite.
Dependencies are inferred from the claim text.