High strength conductive polymers
AssigneeHyperion Catalysis International, Inc.
InventorsPaul R. Nahass, Stephen O. Friend, Robert W. Hausslein
Life of this patent
Estimating the term…
Abstract
A polymeric composition having improved toughness and conductivity comprising carbon fibrils, at least a portion of which are in the form of aggregates, wherein, as measured on an area basis, substantially all of the aggregates are less than about 35 .mu.m in diameter. A polymeric composition having improved toughness and conductivity is prepared by combining carbon fibrils, at least a portion of which are in the form of aggregates, with a polymeric material, mixing the combination to distribute the fibrils in the polymeric material and applying shear to the combination to break down the aggregates until substantially all of the aggregates are less than about 35 .mu.m in diameter.
Claims33
A polymeric composition comprising a polymeric binder and 0.25-50 wt % of graphite carbon fibrils, said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter between 3.5 and 70 nanometers, wherein said composition has IZOD notched impact strength greater than about 2 ft-lbs/in and volume resistivity less than about 1.times.10.sup.11 ohm-cm.
A polymeric composition comprising a polymeric binder and 0.25-50 wt % of graphitic carbon fibrils, said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter between 3.5 and 70 nanometers, wherein said composition has improved toughness and volume resistivity less than 1.times.10.sup.11 ohm-cm, wherein at least a portion of said fibrils are in the form of aggregates and, wherein, as measured on an area basis, substantially all of said aggregates are less than about 35 .mu.m in diameter.
A polymeric composition comprising a polymeric binder and 0.25-50 wt % of graphite carbon fibrils, said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter between about 3.5 and 70 nanometers, wherein at least a portion of said fibrils are in the form of aggregates and wherein, as measured on an area basis, substantially all of said aggregates are less than about 35 .mu.m in diameter, and wherein said composition has volume resistivity less than about 1.times.10.sup.11 ohm-cm.
A polymeric composition comprising 0.25-50 wt % of graphitic carbon fibrils, said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter between 3.5 and 70 nanometers, wherein at least a portion of said fibrils are in the form of aggregates, said composition being substantially free, as measured on an area basis, of fibril aggregates having a diameter greater than about 35 .mu.m and wherein at least 90%, as measured on an area basis, of said fibril aggregates are less than about 25 .mu.m in diameter, wherein said composition has volume resistivity less than about 1.times.10.sup.11 ohm-cm.
A polymeric composition comprising 0.25-50 wt % of graphitic carbon fibrils, said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter between 3.5 and 70 nanometers, wherein said composition has IZOD notched impact strength greater than 75% of the IZOD notched impact strength of said composition without said fibrils and wherein said composition has volume resistivity less than about 1.times.10.sup.11 ohm-cm.
A polymeric composition comprising 0.25-50 wt % of carbon fibrils said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter between about 3.5 and 70 nanometers, wherein at least a portion of said fibrils are in the form of aggregates and wherein, as measured on an area basis, substantially all of said aggregates are less than about 5 .mu.m in diameter.
A polymeric masterbatch composition comprising 1.0-60 wt % of graphic carbon fibrils, said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter between 3.5 and 70 nanometers, wherein at least a portion of said fibrils are in the form of aggregates, said composition being substantially free, as measured on an area basis, of fibril aggregates greater than about 50 .mu.m and wherein, as measured on an area basis, at least 90% of said fibril aggregates are less than about 35 .mu.m in diameter.
A filled polymeric composition having improved toughness and volume resistivity less than 1.times.10.sup.11 ohm-cm, prepared by a process comprising:
- (a) combining between 0.25-50 wt % of graphitic carbon fibrils, said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter between 3.5 and 70 nanometers, with a polymeric material, wherein at least a portion of said fibrils are in the form of aggregates;
- (b) mixing said combination to distribute said fibrils in said polymeric material;
- and
- (c) applying shear to said combination to break down said aggregates until, as measured on an area basis, substantially all of said aggregates are less than about 35 .mu.m in diameter.
A polymeric composition comprising 0.25-50 wt % of graphic carbon fibrils, said fibrils being substantially cylindrical with a substantially constant diameter, having c-axes substantially perpendicular to their cylindrical axis, being substantially free of pyrolytically deposited carbon, and having a diameter Between 3.5 and 70 nanometers, wherein said composition has tensile elongation of at least 75% of the tensile elongation of said composition without said fibrils and wherein said composition has volume resistivity less that about 1.times.10.sup.11 ohm-cm.
Dependencies are inferred from the claim text.