Method and apparatus for forming deposited film
AssigneeCanon Kabushiki Kaisha
InventorsKoichi Matsuda, Takaharu Kondo, Yusuke Miyamoto
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AssigneeCanon Kabushiki Kaisha
InventorsKoichi Matsuda, Takaharu Kondo, Yusuke Miyamoto
Estimating the term…
A plasma CVD method adapted to a roll-to-roll process or the like wherein the change rate of the temperature of the substrate before and after an i-type semiconductor layer is deposited is made rapid so as to prevent diffusion of impurities occurring due to annealing, by constituting the apparatus structure in such a manner that the deposited film is formed on an elongated substrate by the plasma CVD method while heating the elongated substrate moving in an i-layer forming discharge chamber at a rate of 4.degree. C./second or higher immediately in front of an inlet to the discharge chamber and cooling the same at a rate of 4.degree. C./second or higher immediately at the outlet of the discharge chamber so that a stacked-layer type photovoltaic device having a large area and free from scattering of the characteristics is continuously formed without deterioration of the characteristics occurring due to dopant diffusion.
A process for forming a deposited semiconductor film by glow discharge on a continuously moving belt-like substrate which has a first semiconductor layer deposited thereon, which comprises the steps of:
A process for forming a deposited film according to claim 10, wherein the first semiconductor layer has a first conductivity type.
A process for forming a deposited film according to claim 10, wherein the second semiconductor layer formed after the cooling step is an i-type semiconductor layer.
A process for continuously forming a deposited semiconductor film on an elongated moving substrate by plasma CVD in a vacuum chambers which comprises the steps of continuously moving said substrate in a lengthwise direction in said vacuum chamber, while heating said moving substrate immediately before the inlet of a glow discharge region of said vacuum chamber at a rate of 4.degree. C./second or higher, forming said semiconductor film on said moving substrate in said glow discharge region at a deposition rate of 0.1 nm/second to 20 nm/second by plasma CVD, and cooling said moving substrate at a rate of 4.degree. C./second or higher immediately after the outlet of said glow discharge region.
An apparatus for continuously forming a deposited film on an elongated moving substrate, comprising a vacuum chamber for forming a semiconductor layer having p-type or n-type conductivity on said moving substrate and a vacuum chamber for forming a semiconductor having i-type conductivity on said semiconductor layer having p-type or n-type conductivity, which comprises heating means disposed immediately before said vacuum chamber for forming said semiconductor having i-type conductivity and cooling means disposed immediately after said vacuum chamber for forming said semiconductor having i-type conductivity.
A process for forming a deposited film comprising forming a semiconductor having i-type Conductivity on a moving semiconductor substrate having p-type or n-type conductivity by glow discharge, wherein said moving semiconductor substrate having p-type or n-type conductivity is heated at a rate of 4.degree. C./second or higher before entering a region in which said glow discharge is performed.
A process for forming a deposited film which comprises the steps of:
A process for forming a deposited film Which comprises the steps of:
Dependencies are inferred from the claim text.