A multilayer printed circuit board having multilayered circuit copper foils laminated with insulating layers, said copper foils and said insulating layers being alternated with each other, the improvement wherein each of said multilayered circuit copper foils has a metal layer on its surface adhering to one of said insulating layers, wherein the metal layer comprises an alloy selected from the group consisting of Cu--Zn alloy, Ni--Zn alloy, Ni--Sn alloy, Ni--Cu alloy, Pd--P alloy and Ni--P alloy, and the metal layers and insulating layers are cross-linked by chemical bonds through sulfur atoms.