Hot melt adhesives for bonding to sensitive areas of the human body
AssigneeNational Starch and Chemical Investment Holding Corporation
InventorCharles W. Paul
Life of this patent
Estimating the term…
Abstract
A pressure sensitive hot melt adhesive comprising a block copolymer and 60 to 95 parts of a liquid diluent, the adhesive being characterized by a midblock Tg less than -10.degree. C., a G' less than 15.times.10.sup.4 dynes/cm.sup.2 at 10 rad/s, 25.degree. C., a G" of 1 to 6.times.10.sup.4 dynes/cm.sup.2 and a tensile strength greater than 10 psi exhibit superior properties, without the need for any curing operation after cooling.
Claims20
A pressure sensitive hot melt adhesive comprising a high molecular weight block copolymer and 60 to 95 parts by weight oil or other liquid midblock diluent, the adhesive being characterized by a midblock Tg less than -10.degree. C., a G' less than 15.times.10.sup.4 dynes/cm.sup.2 at 10 rad/s (25.degree. C.), a G" of 1 to 6.times.10.sup.4 dynes/cm.sup.2 (25.degree. C.) and a tensile strength greater than 10 psi and requiring no subsequent curing operation after cooling.
A hot melt pressure sensitive adhesive comprising 1 to 20 parts of an A-B-A rubber triblock or radial block copolymer having a viscosity at 25.degree. C. of above 1,000 cP in toluene at a concentration of 20% by weight wherein the polymer blocks A are non-elastomeric polymer blocks which, as homopolymers have glass transition temperatures above 20.degree. C., while the elastomeric polymer blocks B are isoprene, or butadiene which may be partially or substantial hydrogenated or mixtures thereof;
- 0 to 20 parts A-B diblock rubber having a viscosity at 25.degree. C. of above 1,000 cP in toluene at a concentration of 20% by weight;
- 0 to 10 parts by weight of another compatible high molecular weight polymer having a viscosity at 25.degree. C. of above 1,000 cP in toluene at a concentration of 20% by weight;
- 0 to 30 parts by weight end block resin;
- 60 to 95 parts by weight oil or other liquid midblock diluent;
- 0 to 40 parts by weight of a solid tackifier which is compatible with the polymer midblock;
- 0 to 5 parts wax, and 0 to 3 parts by weight anti-oxidant;
- the parts to total 100 parts by weight;
- the adhesive also characterized by a midblock Tg less than -10.degree. C., a G' less than 15.times.10.sup.4 dynes/cm.sup.2 at 10 rad/s (25.degree. C.), a G" of 1 to 6.times.10.sup.4 dynes/cm.sup.2 (25.degree. C.) and a tensile strength greater than 10 psi and requiring no subsequent curing operation after cooling.
Dependencies are inferred from the claim text.