Process including depolymerization in polyester reactor for recycling polyester materials
AssigneeEastman Chemical Company
InventorsBobby J. Sublett, Gary W. Connell
Life of this patent
Estimating the term…
Abstract
Previously used poly(ethylene terephthalate) polyester materials and copolymers thereof, and in particular postconsumer polyester materials, are depolymerized and repolymerized to produce bottle grade polymer containing up to 75% of the previously used material. The process involves the solubilization and depolymerization of the previously used polyester material in a transesterification and/or polymerization mixture containing dimethylterephthalate, ethylene glycol and transesterification products thereof.
Claims20
A process for preparing a polyester product from a polyester material to be recycled comprising:
- preparing a first reaction mixture including (1) a polyester material to be recycled, (2) a diol and (3) a first dicarboxylic or dicarboxylate species effective for transesterification with said diol to produce a second diester species which is effective for polycondensation to produce a polyester product;
- subjecting said first reaction mixture to conditions effective for causing transesterification of said diol and said first species to thereby produce said second species and simultaneously causing depolymerization of said polyester material to be recycled to thereby produce a regenerated species which is also effective for polycondensation to produce a polyester product, whereby to produce a second reaction mixture which contains both said second species and said regenerated species;
- and
- subjecting said second reaction mixture to conditions effective for causing polycondensation of said second species and said regenerated species, whereby to produce a new polyester product which contains units of both said second species and said regenerated species;
- and
- recovering said new polyester product from said reaction mixture.
A process for preparing a new polyester product from up to 75 molar % postconsumer poly(ethylene terephthalate) flake material to be recycled and consisting essentially of ground used soft drink bottle polyester material, said process comprising:
- preparing a first reaction mixture including (1) said postconsumer poly(ethylene terephthalate) flake material, (2) an ethylene glycol component and (3) a dimethyl terephthalate component;
- subjecting said first reaction mixture to conditions effective for causing transesterification of said ethylene glycol component and said dimethyl terephthalate component to thereby produce a first species comprising either monomeric or oligomeric bis-(2-hydroxyethyl) terephthalate or a mixture of monomeric and oligomeric bis-(2-hydroxyethyl) terephthalates and simultaneously causing depolymerization of said postconsumer poly(ethylene terephthalate) flake material to thereby produce a regenerated species also comprising either monomeric or oligomeric bis-(2-hydroxyethyl) terephthalate or a mixture of monomeric and oligomeric bis-(2-hydroxyethyl) terephthalates, whereby to produce a second reaction mixture containing both said first species and said regenerated species;
- subjecting said second reaction mixture to conditions effective for causing polycondensation of said first species and said regenerated species, whereby to produce a new polyester product which contains terephthalate units of both said first species and said regenerated species, the relative quantities of said postconsumer poly(ethylene terephthalate) flake material and said dimethyl terephthalate component charged as reactants into said process being such that the total of said terephthalate units in said new polyester product comprises from about 25 to about 75 molar % of units of said regenerated species and from about 75 to about 25 molar % of units of said first species;
- and
- recovering said new polyester product from said second reaction mixture.
Dependencies are inferred from the claim text.