Process for preparing cyclopentadienyl-type ligands
AssigneePhillips Petroleum Company
InventorsKrisztina Frey, Gabriele von Massow, Helmut G. Alt, M. Bruce Welch
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AssigneePhillips Petroleum Company
InventorsKrisztina Frey, Gabriele von Massow, Helmut G. Alt, M. Bruce Welch
Estimating the term…
In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR.sub.2, --YNR.sub.2, or --NR.sub.2, wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX.sub.3, wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.
A process for preparing a cyclopentadienyl ligand comprising reacting a fulvene compound and a nucleophile;
Dependencies are inferred from the claim text.