# US 5,552,817 A · Electrothermal printing ink with monodispersed synthetic pigment particles and method and apparatus for electronic printing therewith > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,552,817 A - Document ID: US5552817A - Status: Granted - Kind: A - Application number: 08/397,746 - Filed: 1995-03-02 - Granted: 1996-09-03 - Earliest claimed: 1993-12-13 - Inventors: Manfred R. Kuehnle - Web page: https://patentgrep.com/patent/US5552817A ## CPC - G03G 15/751: {relating to drum (G03G15/757 takes precedence)} - B41J 2/415: by passing charged particles through a hole or a slit - C09D 11/02: Printing inks (C09D11/30 takes precedence) - G03G 15/0194: {primary transfer to the final recording medium (G03G15/0184 takes precedence)} - G03G 15/321: {by charge transfer onto the recording material in accordance with the image} - G03G 2215/0103: Plural electrographic recording members - G03G 2215/0631: melted, or otherwise made liquid - G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY - B41J: TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS - C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D) ## Abstract A printing ink comprises a clear, transparent, polymeric carrier material and uniform, colloidal size charged color particles evenly dispersed therein. The carrier and the particles are adhesively bonded to one another so as to form a matrix which can collectively respond to an externally imposed electrostatic field to promote co-movement of a "bite" of ink to an imaging medium without change of the bulk particle/carrier ratio. During the printing process, the ink is melted and exposed to electrostatically charged latent image areas on a heated image cylinder, resulting in the transfer of the ink thereto in proportion to the electrostatic field strength. The ink exhibits a relatively sharp liquid-to-solid transition, thereby enabling rapid ink solidification and complete transfer from the imaging medium to the relatively cool printing substrate. Also disclosed is a printing method and apparatus that facilitate continuous, variable and on-demand color printing in conjunction with the ink. Use of essentially monodispersed, color-coated, colloidal size, spherical particles in the ink results in excellent color purity and chromaticity range. ## Claims ### Claim 1 An electronic printing press comprising: a. a plurality of print stations, each capable of applying ink of a selected color to a printing substrate; b. means for advancing the substrate to successively encounter each print station such that ink is applied on top of ink applied by each other print station; c. wherein such printing station comprises: 1) a generally cylindrical image member having an exterior surface for receiving ink, said image member including a generally cylindrical rigid body having a shaft extending therefrom, a thermally and electrically insulating elastic member encasing the body, a metallic sleeve tightly surrounding the insulating member, a hard, highly dielectric surface of high surface resistivity surrounding said sleeve constituting the exterior surface of the image member, the dielectric surface being thin and flexible and exhibiting a smoothness and surface-energy characteristics to readily release ionic charges in conjunction with a removal of said printing ink therefrom; 2) a writing head disposed exteriorly of said image member and comprising an array of field-emission ionization electrode structures disposed coaxially and in full length proximate to the image member, each electrode structure being spaced a predetermined distance opposite the exterior surface of the image member, and 3) an ink source with an outer surface carrying a layer of liquid ink and moving in unison with the exterior surface of the image member, said ink source and said image member being placed in close proximity to one another to form a nip that can be filled with said ink to form an active reservoir space from which said ink can be extracted. ### Claim 2 (depends on 1) The printing press of claim 1 wherein the field-emission electrode structures each comprise: a. a chimney-like microtunnel, fabricated from an insulating material, having an interior surface and disposed radially above the surface of the image member such that an open end of the microtunnel faces the image member; b. an electrode mounted within the microtunnel and connected to an electrical power supply; and c. a conductive band extending around the inner surface of the microtunnel and in close proximity to the open end of the microtunnel facing the image member, the band being connected to a voltage-control circuit that facilitates application of a first voltage to the band and a second voltage to the image member, and respective adjustment of these voltages. ### Claim 3 (depends on 1) The apparatus of claim 1 wherein the liquid ink comprises: a. a colorless carrier material comprising an electrostatically polarizable polymeric substance which is responsive to an externally imposed electrostatic field, and b. colored, non-melting, evenly dispersed fine particles of composite structure and of colloidal dimensions, whose size, shape, and compositional chemistry are substantially identical and conform to predetermined values, the particles being adhesively integrated in the carrier material to form an interactive matrix therewith. ### Claim 4 (depends on 1) The apparatus of claim 1 wherein the writing head is capable of continuously applying new imagewise electrostatic charges onto said image member during transfer of the ink to said image member according to previously applied charges. ### Claim 5 (depends on 3) The apparatus of claim 3 wherein the carrier material is solid or quasi-solid at temperatures below 80.degree. C., becomes pliable at temperatures between 80.degree. C. and 150.degree. C., and enters a liquid melt phase at temperatures above 150.degree. C., and further wherein the predetermined temperature is at least 150.degree. C. ### Claim 6 (depends on 3) The apparatus of claim 3 wherein the carrier material is a thermoplastic polymer selected from the group consisting of polymethylmethacrylate, polystyrene, polystyrene/polymethylmethacrylate copolymer, polymethylmethacrylate/polybutylmethacrylate copolymer, and polybutylmethacrylate/polystyrene copolymer. ### Claim 7 (depends on 3) The apparatus of claim 3 wherein at least one dye is adsorbed or absorbed into the ink particles. ### Claim 8 (depends on 1) The apparatus of claim 1 further comprising alignment means associated with the electrode structures for aligning the structures with the image member. ### Claim 9 (depends on 1) The apparatus of claim 1 wherein each electrode structure comprises: a. a hollow, insulating rectangular body that defines a gas tunnel; and b. disposed therein, at least one needle electrode. ### Claim 10 (depends on 1) The apparatus of claim 1 further comprising an electrical power supply coupled to each electrode structure and capable of selectably applying voltage pulses thereto, the voltage pulses being of sufficient magnitude to cause breakdown. ### Claim 11 (depends on 10) The apparatus of claim 10 further comprising control circuitry for controlling the magnitudes of the voltage pulses. ### Claim 12 (depends on 10) The apparatus of claim 10 further comprising control circuitry for selectably actuating the electrode structures to form an imagewise charge pattern on the image member. ### Claim 13 (depends on 10) The apparatus of claim 10 further comprising means for removing electrical charges from the image member. ### Claim 14 (depends on 13) The apparatus of claim 13 wherein the charge-removal means is a source of ultraviolet radiation.