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AssigneeMobil Oil Corporation
InventorsClarence D. Chang, Jose G. Santiesteban, David S. Shihabi, Scott A. Stevenson, James C. Vartuli
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There is provided a catalytic method for converting nitrogen oxides to nitrogen (i.e., N.sub.2). The catalyst for this method comprises an acidic solid component comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal and further comprising at least one metal selected from the group consisting of Group IB, Group IVA, Group VB, Group VIIB, Group VIII, and mixtures thereof. An example of this catalyst is zirconia, modified with tungstate, and iron. This method may be used for reducing emissions of nitrogen oxides from waste gases, including industrial exhaust gases and automobile exhaust gases. In a particular embodiment, nitrogen oxides in waste gases may be reacted with ammonia before the waste gases are discharged to the atmosphere.
A method for converting nitrogen oxides to nitrogen by contacting the nitrogen oxides with a reducing agent in the presence of a catalyst which is effective for the reduction of nitrogen oxides, said catalyst consisting essentially an acidic solid component comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal and further containing at least one metal selected from the group consisting of Group IB, Group IVA, Group VB, Group VIIB, Group VIII, and mixtures thereof.
A method for pretreating prior to discharge to the atmosphere an exhaust gas contaminated with NO.sub.x, which method comprises forming at a temperature of at least about 200.degree. C. a mixture of ammonia and the exhaust gas in which the ammonia is present in an amount sufficient to effect reduction of NO.sub.x by reaction with the ammonia, and contacting the mixture at a temperature from about 200.degree. C. to about 600.degree. C. and at a gas hourly space velocity effective to reduce the NO.sub.x content with a selective reduction catalyst consisting essentially of an acidic solid comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal and further containing at least one metal selected from the group consisting of Group IB, Group IVA, Group VB, Group VIIB, Group VIII, and mixtures thereof.
Dependencies are inferred from the claim text.