A method for the separation of catalyst-free working solution from working solution containing noble-metal black as catalyst, obtained in the hydrogenation cycle of the anthraquinone method for the production of hydrogen peroxide comprising filtering the catalyst-containing working solution using filter candles formed of an open-pore inert support body with an average pore width in a range of 5 to 100 .mu.m and of a single-layer or multilayer membrane of ceramic material with an average pore width in a range of at least about 1 up to 10 .mu.m located on one side of and in contact with the support body wherein the catalyst-containing working solution passes through the membrane first.