Tinting hydrogel materials with vat dyes
AssigneePilkington Barnes Hind, Inc.
InventorJohn M. Evans
Life of this patent
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Abstract
Disclosed are processes for tinting hydrogel materials, such as contact lenses, by dissolving a leuco sulfate ester of a vat dye in an compatible monomer solution, adding an oxidizing initiator to the monomer solution, and oxidizing and polymerizing the monomer solution and dye in the same solution. In one aspect, the oxidation and polymerization are conducted simultaneously whereas in another embodiment, the oxidation of the soluble leuco sulfate ester of a vat dye to the insoluble vat dye and polymerization are conducted sequentially in the same reaction medium.
Claims15
A method for the manufacture of tinted hydrogel materials which method comprises:
- (a) dissolving a leuco sulfate ester of a vat dye in a composition comprising a compatible hydrophilic ethylenically unsaturated monomer or mixture of monomers to form a monomer solution;
- (b) adding an oxidizing initiator to the monomer solution produced in (a) above;
- (c) oxidizing said leuco sulfate ester of the vat dye in the monomer solution to an insoluble vat dye;
- and
- (d) polymerizing the monomer composition produced in (c) above by exposing the monomer composition to polymerization conditions.
A method for the manufacture of tinted hydrogel materials which comprises
- (a) dissolving a leuco sulfate ester of a vat dye in a compatible hydrophilic ethylenically unsaturated monomer to form a monomer solution;
- (b) adding an oxidizing initiator to the monomer solution produced in (a) above;
- (c) simultaneously initiating oxidation of the leuco sulfate ester to an insoluble vat dye and polymerization of the monomer composition by exposing the monomer composition to polymerization conditions.
A method for the manufacture of tinted hydrogel materials which comprises
- (a) dissolving a leuco sulfate ester of a vat dye in a compatible hydrophilic ethylenically unsaturated monomer to form a monomer solution;
- (b) adding an oxidizing initiator to the monomer solution produced in (a) above;
- (c) initiating oxidation of said leuco sulfate ester in the monomer solution to an insoluble vat dye which is dispersed throughout the monomer;
- and subsequently
- (d) initiating polymerization of the monomer composition produced in (c) above by exposing the monomer composition to polymerization conditions.
A method for the manufacture of tinted hydrogel materials which comprises
- (a) dissolving a leuco sulfate ester of a vat dye in a compatible hydrophilic ethylenically unsaturated monomer to form a monomer solution;
- (b) adding an oxidizing initiator to the monomer solution produced in (a) above;
- (c) initiating polymerization of the monomer composition produced in (b) above by exposing the monomer composition to polymerization conditions;
- and subsequently
- (d) initiating oxidation of said leuco sulfate ester in the polymer composition produced in (c) above to an insoluble vat dye which is dispersed throughout said polymer composition.
Dependencies are inferred from the claim text.