Functionalization of polymers via enamine of acetoacetate
AssigneeRohm and Haas Company
InventorsAlvin C. Lavoie, Daniel A. Bors, Ward T. Brown
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Abstract
The present invention relates to the preparation of polymers bearing reactive functional groups. More particularly, this invention relates to the preparation of polymers containing functional acetoacetate groups and then following the polymerization reacting the acetoacetate group with a functional amine to form an enamine. Polymers of the present invention have many uses including coatings, sealants, adhesives and saturant applications, and are most useful as solutions or dispersions in water or water-cosolvent mixtures.
Claims5
A process for producing storage stable functional polymers comprising reacting an aqueous acetoacetate-functional polymer with a compound which has primary amine and at least one other type of functional group at conditions which favor formation of the enamine and storing the resulting liquid aqueous composition.
A process for preparing an aqueous polymer having functional groups comprising polymerizing a monomer mixture which contains acetoacetate monomer at conditions which are incompatible with a functional group and then after polymerization, reacting the acetoacetate-functional polymer product with a compound which has primary amine and the incompatible functional group at conditions which favor formation of the enamine.
Dependencies are inferred from the claim text.