Carbonyl sulfide abatement in fluids

Abstract

A method for removing carbonyl sulfide from fluids, particularly gases, involves contacting them with alkaline aqueous solutions containing peroxide and hindered amine. The sulfur products so formed can then be separated from the fluid. In one embodiment, gas containing carbonyl sulfide is cycled through a wet scrubber containing a solution of hydrogen peroxide and methyldiethanolamine, triethylamine, dimethylmonoethanolamine, diethylmonoethanolamine, triethanolamine, 2-amino-2-meth-yl-1-propanol, and/or 1,8-p-menthanediaminemethyldiethanolamine at a pH of about 9 to 11, e.g., about 10. Methyldiethanolamine is preferred in one embodiment. A dispersant such as a water-soluble polymer having a molecular weight of about 500 to 100,000 may optionally be employed in the solution. Abatement of greater than 90% of the carbonyl sulfide is achieved in preferred embodiments.

Dependencies are inferred from the claim text.