Back to results
US 5,516,935 AGranted
Process for the production of diisocyanates
AssigneeBayer Aktiengesellschaft
InventorsEric Bischof, Peter Briedenbach, Jurgen Dahmer, Andreas Flink, Attila Molnar, Herbert Stutz
Life of this patent
Estimating the term…
Abstract
Diisocyanates are produced by gas-phase phosgenation of aliphatic diamines having two primary amino groups in the 1,2- or 1,3-position to one another or by cycloaliphatic diamines having two primary amino groups in the 1,2- or 1,3-position to one another.
Claims6
A process for the production of a diisocyanate comprising
- a) heating a vaporous diamine selected from
- 1) aliphatic diamines having two primary amino groups in the 1,2- or 1,3-positions to one another and
- 2) cycloaliphatic diamines having two primary amino groups in the 1,2- or 1,3-positions to one another to a temperature of from about 200.degree. to about 600.degree. C.,
- b) heating phosgene to a temperature of from about 200.degree. to about 600.degree. C.,
- c) introducing the diamine from step a) and the phosgene from step b) into a cylindrical reaction chamber heated to a temperature of from about 200.degree. to about 600.degree. C., which reaction chamber has no moving pads, in a manner such that a turbulent flow is maintained in the reaction chamber and the diamine from step a) and phosgene from step b) are reacted,
- d) cooling any gas leaving the reaction chamber by means of an inert liquid solvent that is maintained at a temperature above the decomposition temperature of carbamic acid chloride corresponding to the diamine used in step a),
- e) recovering a solution of diisocyanate plus inert liquid solvent, and
- f) distilling the solution recovered in step e) to isolate the product diisocyanate.
5 more elements
Dependencies are inferred from the claim text.