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US 5,516,848 AGranted
Process to produce thermoplastic elastomers
AssigneeExxon Chemical Patents Inc.
InventorsJo Ann M. Canich, Henry W. Yang, Gary F. Licciardi
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Abstract
This invention relates to polypropylene blends, particularly blends of high molecular weight amorphous polypropylene with lower molecular weight isotactic polypropylene. These blends exhibit unusual elastomeric properties.
Claims12
A process for producing a polypropylene composition comprising:
- selecting a first catalyst system comprising an activator and a monocyclopentadienyl transition metal compound capable of producing an amorphous polypropylene having a Mw of at least 150,000 and a Mw/Mn of less than 3;
- selecting a second catalyst system comprising an activator and another bis-cyclopentadienyl transition metal compound capable of producing a crystalline polypropylene having a Mw of less than 300,000 and a Mw/Mn of less than 3;
- provided that the first and second catalyst systems are selected such that the Mw of the amorphous polypropylene is greater than the Mw of the crystalline polypropylene;
- and
- contacting the first and second catalyst systems under polymerization conditions in a polymerization reactor with olefin monomers consisting essentially of propylene to produce a polypropylene composition comprising higher Mw amorphous polypropylene having a Mw of at least 150,000 and a Mw/Mn of less than 3 and lower Mw crystalline polypropylene having a Mw of less than 300,000 and a Mw/Mn of less than 3.
2 more elements
Dependencies are inferred from the claim text.