High molecular weight linked esterified propoxylated glycerins useful as gelling or thickening agents
AssigneesArco Chemical Technology, L.P., CPC International Inc.
InventorsBernard C. Sekula, Michael R. Ferenz
Life of this patent
Estimating the term…
Abstract
Reduced calorie food compositions are prepared using linked esterified alkoxylated polyol fat substitutes comprised of polycarboxylate linking segments, polyol segments, and C.sub.6 -C.sub.24 monocarboxylic fatty acid-esterified oxyalkylene segments, and, optionally, oxyalkylene segments between the polycarboxylate linking segments and the polyol segments. The fat substitutes are obtainable by alkoxylating a polyol such as glycerin with an epoxide such as propylene oxide and esterifying the resulting alkoxylated polyol with both a polycarboxylic acid or an equivalent thereof and a C.sub.6 -C.sub.24 monocarboxylic fatty acid or an equivalent thereof, either simultaneously or sequentially.
Claims8
A composition useful as a reduced calorie fat substitute comprising:
- (a) a liquid non-linked esterified propoxylated glycerin;
- and
- (b) a linked esterified propoxylated glycerin comprised of:
- (i) at least two polycarbonyl linking segments;
- (ii) at least three glyceryl segments;
- and
- (iii) at least one C.sub.6 -C.sub.24 monocarboxylic fatty-acid esterified oxypropylene segment attached to a glyceryl segment;
- wherein each glyceryl segment is connected to a polycarbonyl linking segment either directly or through an oxypropylene segment and the linked esterified propoxylated glycerin has a molecular weight greater than 6000.
A method of suppressing the tendency of a liquid non-linked esterified propoxylated glycerin fat substitute to exhibit anal oil leakage when consumed comprising incorporating into said liquid non-linked esterified propoxylated glycerin fat substitute a linked esterified propoxylated glycerin comprised of:
- (a) at least two polycarbonyl linking segments;
- (b) at least three glyceryl segments;
- and
- (c) at least one C.sub.6 -C.sub.24 monocarboxylic fatty acid esterified oxypropylene segment attached to a glyceryl segment, wherein each glyceryl segment is connected to a polycarbonyl linking segment either directly or through an oxypropylene segment and the linked esterified propoxylated glycerin has a molecular weight greater than 6000.
Dependencies are inferred from the claim text.