Esterified alkoxylated polyol fat substitutes having high primary ester content
AssigneesArco Chemical Technology, L.P., CPC International Inc.
InventorsCharles F. Cooper, Stephen H. Harris
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Abstract
Reduced calorie food compositions are prepared using fatty acid esterified alkoxylated polyol fat substitutes derived from C.sub.3 and higher epoxides and having a high proportion of primary ester linkages. The fat substitutes may be obtained by alkoxylation of a polyol such as glycerin with the epoxide in the presence of a cationic/ring-opening polymerization catalyst, followed by esterification with a fatty acid or a fatty acid equivalent.
Claims6
An esterified propoxylated glycerin composition suitable for use as a reduced calorie fat substitute wherein
- (a) from 3 to 21 oxypropylene units derived from propylene oxide per equivalent of glycerin attached by ether linkages to glycerin are present;
- from 2 to 3 C.sub.6 -C.sub.24 fatty acid acyl groups per equivalent of glycerin attached through ester linkages are present;
- (c) at least 40% of the ester linkages are primary ester linkages;
- and
- (d) said esterified propoxylated glycerin composition is characterized by the absence of oxyalkylene units derived from ethylene oxide.
An esterified propoxylated glycerin composition useful as a reduced calorie fat substitute obtainable by a process comprising
- (a) reacting propylene oxide with glycerin in the absence of ethylene oxide and the presence of an effective amount of a cationic ring-opening polymerization catalyst to form a propoxylated glycerin intermediate wherein at least 40% of the hydroxyl end-groups of said propoxylated glycerin intermediate are primary hydroxyl end-groups and containing from 3 to 21 equivalents of propylene oxide per equivalent of glycerin;
- and
- (b) reacting the propoxylated glycerin intermediate with a fatty acid entity selected from the group consisting fatty acids, fatty acid anhydrides, fatty acid halides, and alkyl esters of fatty acids to form the esterified propoxylated glycerin composition.
Dependencies are inferred from the claim text.