Saturate reduction in normal alpha olefins using a cobalt-containing transalkylation catalyst
AssigneeChevron Chemical Company
InventorsLoren W. Hedrich, Alfred N. Kresge, Roger C. Williamson
Life of this patent
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Abstract
Disclosed is a process for producing normal alpha olefins having less than 1.0% saturates content, and typically no more than 0.40% saturates content. The process involves forming a mixture of normal alpha olefins and tri(higher)alkyl aluminum compounds, contacting this mixture with a cobalt-containing transalkylation catalyst, and hydrolyzing the normal alpha olefin/transalkylation catalyst mixture to minimize the amount of saturates formed. In one embodiment, the catalyst is a cobalt- and nickel-containing transalkylation catalyst. After hydrolysis, the resulting normal alpha olefins contain essentially no Group VIII metal that is capable of transalkylation.
Claims20
A process for producing normal alpha olefins having less than 1.0% saturates content, said process comprising:
- (a) contacting a trialkyl aluminum compound and ethylene under alpha-olefin formation conditions thereby producing a mixture comprising normal alpha olefins and tri(higher)alkyl aluminum compounds;
- (b) contacting at least a portion of said mixture and sufficient ethylene, in the presence of a cobalt-containing transalkylation catalyst, thereby transalkylating substantially all of said tri(higher)alkyl aluminum compounds, said transalkylation catalyst being used in an amount and under conditions which cause transalkylation of said tri(higher)alkyl aluminum compounds, but not isomerization of said normal alpha olefins;
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- (c) contacting the mixture produced by step (b) with a sufficient amount of aqueous acid or caustic, and water, to produce an organic phase and an aqueous phase, wherein said organic phase has essentially all of said transalkylation catalyst removed.
In a process for producing normal alpha olefins by contacting a trialkyl aluminum compound and ethylene under alpha olefin formation conditions, thereby producing a mixture comprising normal alpha olefins and tri(higher)alkyl aluminum compounds, and hydrolyzing said mixture, the improvement comprising contacting said mixture of normal alpha olefins and tri(higher)alkyl aluminum compounds, prior to hydrolysis, with ethylene and a cobalt-containing transalkylation catalyst under transalkylation conditions, said transalkylation catalyst being used in an amount and under conditions sufficient to cause transakylation but insufficient to cause isomerization of said normal alpha olefins, wherein said normal alpha olefins contain essentially no transalkylation catalyst after hydrolysis.
In a process for producing normal alpha olefins by contacting a trialkyl aluminum compound and ethylene under alpha olefin formation conditions, thereby producing a mixture comprising normal alpha olefins and tri(higher)alkyl aluminum compounds, and hydrolyzing said mixture, the improvement comprising contacting said mixture of normal alpha olefins and tri(higher)alkyl aluminum compounds, prior to hydrolysis, with ethylene and a cobalt-containing transalkylation catalyst under transalkylation conditions, said transalkylation catalyst being used in an amount and under conditions sufficient to cause transalkylation but insufficient to cause isomerization of said normal alpha olefins, wherein said normal alpha olefins contain essentially no Group VIII metal after hydrolysis.
Dependencies are inferred from the claim text.