Carbamate-functional polyester polymer or oligomer and coating composition
AssigneeBASF SE
InventorsGregory L. Menovcik, Walter H. Ohrbom
Life of this patent
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Abstract
Polyester polymers having pendant carbamate groups are disclosed. The polymers are prepared by reacting: (a) reacting a hydroxyalkyl cyclic carbonate compound with a compound having at least one cyclic anhydride group to form a half-ester acid comprising a cyclic carbonate group, (b) reacting the cyclic carbonate group on the half-ester from step (a) with ammonia, ammonium hydroxide, or a primary amine to ring open the cyclic carbonate and form a compound comprising an acid group, a hydroxyl group, and a pendant carbamate group, and (c) reacting a mixture comprising the compound from step (b) and optionally comprising a polyol or a polyacid or both to form the polyester having pendant carbamate groups.
Claims19
A method of preparing a polyester having pendant carbamate groups, comprising the steps of:
- (a) reacting a hydroxyalkyl cyclic carbonate compound with a compound having at least one cyclic anhydride group to form a half-ester acid comprising a cyclic carbonate group,
- (b) reacting the cyclic carbonate group on the half-ester from step (a) with ammonia, ammonium hydroxide, or a primary amine to ring open the cyclic carbonate and form a compound comprising an acid group, a hydroxyl group, and a pendant carbamate group, and
- (c) polymerizing a mixture comprising compounds from step (b) and optionally comprising a polyol or a polyacid or both to form the polyester having pendant carbamate groups.
A polyester having pendant carbamate groups that is the esterification reaction product of a mixture comprising:
- (1) compounds comprising at least one acid group, at least one hydroxyl group, and at least one pendant carbamate group, and
- (2) optionally, a polyol or a polyacid or both.
A curable coating composition comprising:
- (A) a polyester that is the esterification reaction product of a mixture comprising:
- (1) compounds comprising at least one acid group, at least one hydroxyl group, and at least one pendant carbamate group, and
- (2) optionally, a polyol or a polyacid or both, and
- (B) a curing agent having a plurality of groups that are reactive with carbamate.
Dependencies are inferred from the claim text.