Superconducting composite
AssigneeSumitomo Electric Industries, Ltd.
InventorsKenichiro Sibata, Takeshi Yamaguchi, Shuji Yazu, Tetsuji Jodai
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Abstract
Superconducting composite comprising a matrix made of superconducting sintered mass composed of perovskite type or quasi-perovskite type oxide and metal phase dispersed in the superconducting mass with a proportion of from 10 to 70 volume % with respect to said composite. The metal phase may consist of at least one of Cu, Ag, Au, Pt, Ni and Zn or their alloys. The superconducting sintered mass may be Ba-Y-Cu-O type compound oxide.
Claims12
A process for producing a superconducting composite comprising a superconducting sintered mass composed of perovskite or quasi-perovskite oxide represented by one of the following general formula (I) or (II):
- Y.sub.a Ba.sub.1-a Cu.sub.y O.sub.z (I)
- La.sub.a Sr.sub.1-a Cu.sub.y O.sub.z (II)
- wherein a is 0.4-0.6 and y is 0.5-1 in Formula I and a is 0.4 and y is 1 in Formula II, and "z" represents a number which is selected from a range of from 1 to 5, and
- a metal phase dispersed in said superconducting mass with a proportion of from 10 to 70 volume % in the composite, the metal of the metal phase possessing higher heat-conductivity and higher specific heat than the surrounding sintered mass;
- said process comprising the steps of:
- preparing a powder mixture comprising a powder of oxide or carbonate of Sr or Ba, a powder of oxide or carbonate of La or Y and a powder of oxide or carbonate of Cu in such proportions that the atom ratio of said elements "Sr or Ba":"La or Y":Cu is adjusted to that defined in Formulae I and II,
- subjecting the powder mixture to preliminary sintering,
- pulverizing a preliminary sintered mass,
- admixing metal powder with the resulting pulverized powder,
- compacting the resulting metal-containing powder mixture into a shaped body, and
- subjecting the shaped body to the final sintering to producing a superconducting composite comprising a metal phase dispersed in a superconducting material.
A process for producing a superconducting composite comprising a superconducting sintered mass composed of perovskite or quasi-perovskite oxide represented by one of following general formula (I) or (II):
- Y.sub.a Ba.sub.1-a Cu.sub.y O.sub.z (I)
- La.sub.a Sr.sub.1-a Cu.sub.y O.sub.z (II)
- wherein a is 0.4-0.6 and y is 0.5-1 in Formula I and a is 0.4 and y is 1 in Formula II, and "z" represents a number which is selected from a range of from 1 to 5, and
- a metal phase dispersed in said superconducting mass with a proportion of from 10 to 70 volume % in the composite, the metal of the metal phase possessing higher heat-conductivity and higher specific heat than the surrounding sintered mass;
- said process comprising the steps of:
- preparing a powder mixture comprising a powder of oxide or carbonate of Sr or Ba, a powder of oxide or carbonate of La or Y and a powder of oxide or carbonate of Cu in such proportions that the atom ratio of said elements "Sr or Ba":"La or Y":Cu is adjusted to that defined in Formulae I and II,
- subjecting the powder mixture to preliminary sintering,
- pulverizing a preliminary sintered mass,
- compacting the resulting pulverized powder into a shaped porous body,
- subjecting said shaped porous body to the final sintering, and then
- dipping said sintered shaped porous body in molten metal so that a matrix of said sintered porous shaped body is impregnated with the metal.
Dependencies are inferred from the claim text.