Tabularly banded emulsions with high chloride central grain portions
AssigneeEastman Kodak Company
InventorJoe E. Maskasky
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Abstract
Radiation-sensitive emulsions are disclosed in which tabular grains of a face centered cubic crystal lattice structure having parallel {111} major faces and an average aspect ratio of at least 5 are comprised of a central region containing greater than 50 mole percent chloride and a tabular band containing less than 40 mole percent chloride and extending laterally outwardly from the central region to form at least 25 percent of the {111} major faces.
Claims11
A radiation-sensitive emulsion comprised of a dispersing medium and silver halide grains, at least 50 percent of total grain projected area being accounted for by tabular grains of a face centered cubic crystal lattice structure having parallel {111} major faces and an average aspect ratio of at least 5, the tabular grains each being comprised of a central region and a shell differing in halide content, wherein
- the halide content of the central region is greater than 50 mole percent chloride,
- the halide content of the shell is less than 40 mole percent chloride,
- the shell is comprised of a band extending laterally outwardly from the central region and forming at least 25 percent of the {111} major faces, the band accounting for at least half the volume of the shell, and
- the emulsion contains a 4,5,6-triaminopyrimidine, a polyiodophenol or an iodo-8-hydroxyquinoline grain growth modifier.
A radiation-sensitive emulsion comprised of a dispersing medium and silver halide grains, at least 70 percent of total grain projected area being accounted for by tabular grains of a face centered cubic crystal lattice structure having parallel {111} major faces, an average thickness of less than 0.2 .mu.m, and an average aspect ratio of at least 5, the tabular grains each being comprised of a central region and a shell differing in halide content, wherein
- the halide content of the central region is at least 70 mole percent chloride,
- the halide content of the shell is at least 70 mole percent bromide,
- the shell is comprised of a band extending laterally outwardly from the central region between the {111} major faces and forming at least 25 percent of the {111} major faces, the band accounting for at least 70 percent of the volume of the shell, and
- the emulsion contains a 4,5,6-triaminopyrimidine, a polyiodophenol or an iodo-8-hydroxyquinoline grain growth modifier.
Dependencies are inferred from the claim text.