Composition and method for treating substrates to reduce electrostatic charge and resultant article
AssigneeHenkel Corporation
InventorMichael J. Incorvia
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Abstract
Antistatic agents and their use in processing textiles or formed plastic substrates. The antistatic agent comprises a compound having a fluorocarbon moiety and an ethoxylated quaternary ammonium moiety. The antistatic composition increases the electrolytic conductivity of treated textile or plastic materials, thereby increasing the rate of electrostatic charge dissipation thereof. The antistatic agents remain effective after exposure of the treated substrate to an aqueous environment.
Claims17
A method for dissipating an electrostatic charge on a static-prone substrate comprising incorporating into said substrate an antistatic agent of the formula Q--L--(R--X).sub.d, wherein Q represents a normal or branched, saturated or unsaturated perfluoroaliphatic radical, L represents an ester or an ether linkage, R represents an alkylene-oxyalkylene or an alkylene-poly(oxyalkylene) group, and X represents at least one quaternary ammonium group of the formula ##STR8## and, optionally, a tertiary amine group of the formula ##STR9## wherein R.sub.1 and R.sub.4 independently represent --(C.sub.2 H.sub.4 O).sub.f --Z, Z being H, Q or ##STR10## wherein Q is as defined above, f being an integer from 1 to 50, R.sub.2 represents a C.sub.1 -C.sub.4 alkyl group, R.sub.3 and R.sub.5 independently represent a normal or branched, saturated or unsaturated C.sub.6 -C.sub.22 aliphatic group, A represents an organic or inorganic anion and d is 1 or 2 in an amount effective to impart to said substrate a surface resistance value in the range of from about 10.sup.6 to about 10.sup.12 ohms, a 90% electrostatic charge decay time of 10 seconds or less, or both.
An article of manufacture comprising a substrate selected from the group consisting of a textile substrate, a formed, thermoplastic substrate and a formed, thermoset substrate having incorporated therein the antistatic agent of the formula Q--L--(R--X).sub.d, wherein Q represents a normal or branched, saturated or unsaturated perfluoroaliphatic radical, L represents an ester or an ether linkage, R represents an alkylene-oxyalkylene or an alkylene-poly(oxyalkylene) group, and X represents at least one quaternary ammonium group of the formula ##STR17## and, optionally, a tertiary amine group of the formula ##STR18## wherein R.sub.1 and R.sub.4 independently represent --(C.sub.2 H.sub.4 O).sub.f --Z, Z being H Q or ##STR19## wherein Q is as defined above, f being an integer from 1 to 50, R.sub.2 represents a C.sub.1 -C.sub.4 alkyl group, R.sub.3 and R.sub.5 independently represent a normal or branched, saturated or unsaturated C.sub.6 -C.sub.22 aliphatic group, A represents an organic or inorganic anion and d is 1 or 2.
Dependencies are inferred from the claim text.