Highly reactive zerovalent metals from metal cyanides
AssigneeBoard of Regents of the University of Nebraska
InventorReuben D. Rieke
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Abstract
Novel zerovalent metal species and organometallic reagents are disclosed. The zerovalent metal species are directly produced by reaction of a reducing agent on a metal cyanide salt. Preferably, the zerovalent metal species are directly produced by reaction of an alkali metal reducing agent with a metal cyanide salt. The organometallic reagent results from the reaction of the zerovalent metal species and an organic compound having one or more stable anionic leaving groups.
Claims3
A finely divided zerovalent metal species comprising a combination of formally zerovalent metal atoms selected from the group consisting of Zn, Al, Mg, Ni, Fe, Cr, W, Pt, Pd, Ag, Au, U, Mn, V, Sn, Pb, In, Co, Cd, Tl, Ti, Sm, and Mo and a cyanide salt.
Dependencies are inferred from the claim text.