Hydrogen recovery by adsorbent membranes
AssigneeAir Products and Chemicals, Inc.
InventorsMadhukar B. Rao, Shivaji Sircar
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Abstract
A composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate is utilized to separate hydrogen-hydrocarbon mixtures and a sweep gas comprising some of the same hydrocarbons is passed across the low pressure side of the membrane to enhance hydrocarbon permeability. Methane is an effective sweep gas which promotes the permeation of heavier hydrocarbons even when methane is present in the membrane feed.
Claims8
A method for the recovery of hydrogen from a gaseous feed mixture comprising said hydrogen and one or more hydrocarbons, wherein said hydrocarbons are more strongly adsorbed on an adsorbent material than said hydrogen, said method comprising:
- (a) passing said feed mixture into a separator containing a composite semipermeable membrane consisting essentially of microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator a nonpermeate product stream enriched in said hydrogen, wherein portions of said hydrocarbons are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase, and further wherein contacting of said gaseous feed mixture with said membrane and permeation of components through said membrane occur in the absence of chemical reaction;
- (b) withdrawing from the permeate side of said membrane a permeate comprising said hydrocarbons;
- and
- (c) passing a sweep gas across the permeate side of said membrane and withdrawing from said separator a sweep gas/permeate effluent stream, wherein said sweep gas comprises one or more of the same hydrocarbons present in said feed mixture.
Dependencies are inferred from the claim text.