Contact lenses and materials and methods of making same
AssigneePilkington Barnes Hind, Inc.
InventorsWilliam J. Burke, Lisa A. Folk, Donald J. Ratkowski
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Abstract
An interpenetrating network copolymer, method of producing same, and method of producing optical lens blanks and finished lenses therefrom. The method broadly involves the preparation of first and second mixtures of polymerizable vinyl monomers and interrupting the polymerization of the first mixture at a relative viscosity of from about 1.05 to about 10 by admixing the partially polymerized first mixture with the second mixture to create a casting solution and thereafter, when desired, polymerizing molded casting solution in heat to create a solid lens material.
Claims21
A method of producing an optical lens blank having an interpenetrating network copolymer composition, said method comprising:
- preparing, in weight percent of the weight of all polymerizable vinyl monomers in the network copolymer composition (W/W), a first mixture of polymerizable vinyl monomers containing from about 5% to about 95% (W/W) of polymerizable vinyl monomers, from about 0.01% up to about 35% of a polymerizable monomeric vinyl crosslinking agent, and from about 0.1% up to about 3% (W/W) of a vinyl polymerization initiator;
- preparing a second mixture of polymerizable vinyl monomers containing from about 5% up to about 95% (W/W) of polymerizable vinyl monomers, from about 0.1% up to about 25% of a polymerizable monomeric vinyl crosslinking agent, and from about 0% up to about 0.3% (W/W) of a vinyl polymerization initiator;
- polymerizing said first mixture until said partially polymerized first mixture obtains a relative viscosity relative to said unpolymerized first mixture of from about 1.05 up to about 10;
- interrupting the polymerization of said partially polymerized first mixture by mixing said second mixture therein to create a casting solution therewith;
- introducing said casting solution into a mold having at least one lens finishing surface therein;
- closing said molds;
- heating said closed mold in the range of from about 20.degree. C. up to about 70.degree. C. for a time sufficient to complete the polymerization of said casting solution and create a lens blank having at least one optical surface in said mold;
- removing the closed mold from an oven;
- and removing said blank from said mold.
Dependencies are inferred from the claim text.