Copolymers based on dicarboximides, alkenyl isocyanates and/or alkenylurethanes
AssigneeBASF SE
InventorsStefan Beckmann, Rudolf Zentel, Michael Doerr, Manfred Eich
Life of this patent
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Abstract
A copolymer based on monomers selected from the group consisting of dicarboximides, alkenyl isocyanates and alkenylurethanes of formula I: ##STR1## where R.sup.1 to R.sup.5, R.sup.6, X, Y, Z, M, and a-d are as defined in the specification.
Claims5
A copolymer based on monomers selected from the group consisting of dicarboximides, alkenyl isocyanates and alkenylurethanes of the formula I ##STR22## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5, independently of one another are each selected from the group consisting of hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkyl which contains hetero atoms and substituted C.sub.1 -C.sub.20 -alkyl;
- R.sup.6 is hydrogen or C.sub.1 -C.sub.10 -alkyl which is unsubstituted or substituted by phenyl or hydroxyl, or is C.sub.3 -C.sub.8 -cycloalkyl, or is phenyl or benzyl, each of which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxy groups, or is phenethyl, diphenylmethyl, naphthyl, carbazoyl, isobornyl, adamantyl or 9-fluorenyl;
- X is O or NH;
- Y is methylene, ethylene, propylene, isopropylene, straight-chain or branched C.sub.1 -C.sub.20 -alkylene, ##STR23## where n is from 1 to 15, Z is hydrogen or a radical of formula V ##STR24## where R.sup.7 to R.sup.10 are identical or different and are each H, straight-chain or branched C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy or C.sub.3 -C.sub.7 cycloalkyl,
- I is O or NR.sup.11,
- R.sup.11 is H, C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.7 -cycloalkyl, phenyl, benzyl or phenethyl,
- u and v are each.0 or 1,
- X is CH or N and
- G is CN, NO.sub.2, dicyanovinyl, tricyanovinyl, CHO or CH.dbd.C(CO.sub.2 R.sup.11), or a radical of the formula VI:
- where ##STR25## n is 0 or 1, R.sup.12 and R.sup.13, independently of one another, are each hydrogen, straight-chain or branched C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy or C.sub.3 -C.sub.7 -cycloalkyl.
- I is O or NR.sup.14 wherein
- R.sup.14 is hydrogen C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.7 -cycloalkyl, ##STR26## where n is 0 or 1, Y.sup.1 is hydrogen or methyl and Y.sup.2 is hydrogen or phenyl, and
- E is a radical of a diazo component which is derived from a five-membered aromatic heterocyclic amine which has from one to three hetero atoms selected from the group consisting of nitrogen, oxygen and sulfur in the heterocyclic ring and may be fused with a benzene, thiophene, pyridine or pyrimidine ring;
- M is any copolymerizable monomer and a+b+c+d=1, where
- a and c each range from 0.3 to 0.7 and
- b and d each range from 0 to 0.3.
Dependencies are inferred from the claim text.