Process for production of stabilized polycarbonate
AssigneeTeijin Limited
InventorsMasumi Hirata, Wataru Funakoshi, Katsushi Sasaki
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Abstract
A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfanate group and a sulfonic acid anhydride group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
Claims14
A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of
- a compound of the formula (II)
- .sup.+ X.sup.2 --A.sup.2 --Y.sup.1 --SO.sub.3.sup.- (II)
- wherein A.sup.2 is a divalent hydrocarbon group,
- .sup.+ X.sup.2 is a secondary, tertiary or quaternary ammonium cation or a secondary, tertiary or quaternary phosphonium cation, and
- Y.sup.1 is a single bond or an oxygen atom,
- and a compound of the formula (III)
- A.sup.3 --(.sup.+ X.sup.3).sub.n.(R--Y.sup.1 --SO.sub.3.sup.31).sub.n(III)
- wherein A.sup.3 is a hydrocarbon group having a valence of n,
- .sup.+ X.sup.3 is a secondary, tertiary or quaternary ammonium cation or a secondary, tertiary or quaternary phosphonium cation,
- R is a monovalent hydrocarbon group,
- n is an integer of 2 to 4, and
- Y.sup.1 is a single bond or an oxygen atom,
- in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
Dependencies are inferred from the claim text.