Matte, biaxially oriented, multilayer polypropylene film of high shrinkage, process for the production thereof, and the use thereof
AssigneeHoechst Aktiengesellschaft
InventorsHerbert Peiffer, Ursula Murschall, Gunter Schloegl
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Abstract
The invention relates to a heat-sealable, shrinkable multilayer polypropylene film which comprises at least one base layer containing a propylene polymer or a propylene polymer mixture and at least one outer layer which comprises a mixture or a blend of two components I and II. The mixture contains copolymers and terpolymers of .alpha.-olefins having 2 to 10 carbon atoms and HDPE. The film has a longitudinal shrinkage of >20 and a transverse shrinkage of >25% at 120.degree. C.
Claims16
A multilayer polypropylene film of high shrinkage having at least one matte surface, comprising:
- at least one base layer which comprises a propylene polymer or a propylene polymer mixture;
- and at least one outer layer which comprises a mixture or a blend of two components I and II, wherein
- component I is selected from the group consisting of
- a propylene homopolymer,
- a copolymer of ethylene and propylene,
- a copolymer of ethylene and butylene,
- a copolymer of propylene and butylene,
- a copolymer of ethylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a copolymer of propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a terpolymer of ethylene and propylene and butylene,
- a terpolymer of ethylene and propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- mixture or blends thereof and
- a blend of two or more of said homopolymers, copolymers and terpolymers, mixed with one or more of said homopolymers, copolymers and terpolymers,
- and
- component II is selected from the group consisting of an HDPE and a blend of two components A and B,
- where
- blend component A essentially comprises an HDPE and
- blend component B is selected from the group consisting of
- a propylene homopolymer,
- a copolymer of ethylene and propylene,
- a copolymer of ethylene and butylene,
- a copolymer of propylene and butylene,
- a copolymer of ethylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a copolymer of propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a terpolymer of ethylene and propylene and butylene
- a terpolymer of ethylene and propylene and another .alpha.-olefin having 5 to 10 carbon atoms and
- mixtures or blends thereof,
- and the multilayer film has a longitudinal shrinkage of greater than about 20%, and a transverse shrinkage of greater than about 25%, both measured at 120.degree. C.
A multilayer polypropylene film of high shrinkage having at least one matte surface, comprising:
- at least one base layer which comprises a propylene polymer or a propylene polymer mixture;
- and at least one outer layer which comprises a mixture or a blend of two components I and II, wherein
- component I is selected from the group consisting of
- a propylene homopolymer,
- a copolymer of ethylene and propylene,
- a copolymer of ethylene and butylene,
- a copolymer of propylene and butylene,
- a copolymer of ethylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a copolymer of propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a terpolymer of ethylene and propylene and butylene,
- a terpolymer of ethylene and propylene and another .alpha.-olefin having 5 to 10 carbon atoms, mixture or blends thereof and
- a blend of two or more of said homopolymers, copolymers and terpolymers, mixed with one or more of said homopolymers, copolymers and terpolymers,
- and
- component II is selected from the group consisting of an HDPE and a blend of two components A and B, where blend component A essentially comprises an HDPE and
- blend component B is selected from the group consisting of
- a propylene homopolymer,
- a copolymer of ethylene and propylene,
- a copolymer of ethylene and butylene,
- a copolymer of propylene and butylene,
- a copolymer of ethylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a copolymer of propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a terpolymer of ethylene and propylene and butylene
- a terpolymer of ethylene and propylene and another .alpha.-olefin having 5 to 10 carbon atoms and
- mixtures or blends thereof,
- and the multilayer film has a longitudinal shrinkage of greater than about 20%, and a transverse shrinkage of greater than about 25%, both measured at 120.degree. C., and wherein said multilayer film is made by a process comprising the steps of coextruding the melts corresponding to the individual layers of the film through a flat-film die, taking the coextruded film off over a take-off roll whose temperature is between about 20.degree. and 100.degree. C., biaxially stretching the film at a longitudinal stretching ratio (S.sub.t) from about 4:1 to 9:1 and a transverse stretching ratio (S.sub.1) from about 6:1 to 10:1, heat-setting the biaxially stretched film, and subsequently winding the film up.
Dependencies are inferred from the claim text.