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US 5,493,049 AGranted
Fluorinated compounds containing hetero atoms and polymers thereof
AssigneeDow Corning Corporation
InventorGerardo Caporiccio
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Abstract
This invention provides 1) novel reactive fluorinated compounds derived from a specified class of telomers or cotelomers of fluoroolefins; and 2) stable products and stable polymers thereof obtained by reaction or polycondensation of the novel reactive fluorinated compounds with specified classes of hydrogenated aliphatic, alicyclic, aromatic reactive compounds, telechelic oligomers and block polymers wherein said stable products and polymers contain hetero atoms such as oxygen, sulfur or nitrogen and are characterized by high thermal and chemical resistance.
Claims2
Fluorinated compounds represented by the formula
- R.sup.1 [(R.sup.2 R.sup.4).sub.v (R.sup.2 R.sup.5).sub.w ].sub.k R.sup.2 R.sup.1
- wherein R.sup.1 is selected from the group consisting of
- (a) monovalent telomers of a fluorinated olefin selected from the group consisting of chlorotrifluoroethylene, vinylidene fluoride and trifluoroethylene, and
- (b) monovalent cotelomers of combinations selected from the group consisting of
- (1) chlorotrifluoroethylene and a fluoropropene selected from the group consisting of hexafluoropropene and 2-hydropentafluoropropene,
- (2) chlorotrifluoroethylene and hexafluoropropene,
- (3) chlorotrifluoroethylene and vinylidene fluoride,
- (4) chlorotrifluoroethylene and tetrafluoroethylene,
- (5) chlorotrifluoroethylene, tetrafluoroethylene and a fluoropropene selected form the group consisting of hexafluoropropene and 2-hydropentafluoropropene,
- (6) vinylidene fluoride and a fluoropropene selected from the group consisting of hexafluoropropene, 1-hydropentafluoropene and 2-hydropentafluoropropene
- (7) vinylidene fluoride, chlorotrifluoroethylene and hexafluoropropene,
- (8) tetrafluoroethylene, vinylidene fluoride and chlorotrifluoroethylene, and
- (9) tetrafluoroethylene, vinylidene fluoride and a fluoropropene selected from the group consisting of hexafluoropropene, 1-hydropentafluoropropene and 2-hydropentafluoropropene,
- R.sup.2 represents a bivalent radical connecting R.sup.5 with R.sup.1 and R.sup.4, and is selected from the group consisting of dimethylene, trimethylene, ethyleneoxy, trimethyleneoxy, bistrifluoromethyl)methyleneoxy, hexafluoroisopropylidene, and 2,2-dimethyl-1,3-trimethylene;
- R.sup.4 is a bivalent radical derived from telomers and cotelomers of the same olefins as R.sup.1 ;
- and R.sup.5 represents the divalent group --OC(O)A(O)CO--, where A is alkylene or arylene and said group is derived from an aromatic or aliphatic diester;
- k is from 1 to 500, inclusive;
- v is from 1 to 100, inclusive;
- and w is from 1 to 10, inclusive.
16 more elements
Dependencies are inferred from the claim text.