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US 5,492,539 AGranted
Method of preparing leather from unhaired hides
AssigneeRohm Co., Ltd.
InventorsHarald Bauer, Juergen Christner, Gertrud Wick
Life of this patent
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Abstract
Tanning agents containing an .omega.,.omega.-dialdehyde as as the active tanning substance, optionally in a deactivated form, in combination with a polymer containing hydroxyl groups, and methods for using such tanning agents in the preparation of leather, particularly in pickling, tanning, and retanning.
Claims7
The method of preparing leather from unhaired hides which comprises contacting said hides with a tanning agent comprising as the active tanning agent an .omega.,.omega.'-dialdehyde of the formula
- O.dbd.CH--(CH).sub.r --HC.dbd.O,
- wherein r is an integer from 2 to 8, and a polymer containing hydroxyl groups which is made up of
- a') 0 to 10 percent by weight of at least one carboxylic monomer of the formula
- R.sub.2 HC.dbd.C(R.sub.1)--COOH,
- wherein R.sub.1 is hydrogen, methyl, or a --CH.sub.2 COOH group and R.sub.2 is hydrogen, methyl, phenyl, or a --COOH group but where there are not more than two carboxyl groups in the molecule, or of at least one anhydride monomer of the formula ##STR12## wherein A is the group ##STR13## or the group ##STR14## and b') 0 to 10 percent by weight of at least one hydroxylic monomer of the formula ##STR15## wherein R.sub.3 is hydrogen or methyl and R.sub.4 is an alkyl or cycloalkyl group having 1 to 12 carbon atoms substituted with at least one hydroxyl group, and
- c') 90 to 100 percent by weight of at least one allyloxy ester monomer of the formula ##STR16## wherein R.sub.5 is an alkyl group having 1 or 2 carbon atoms, and d') 0 to 10 percent by weight of at least one (meth)acrylic acid ester monomer of the formula ##STR17## wherein R'.sub.3 is hydrogen or methyl and R.sub.6 is an alkyl or cycloalkyl group having 1 to 12 carbon atoms.
3 more elements
Dependencies are inferred from the claim text.