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US 5,491,271 AGranted
Detergent alkylation using a regenerable clay catalyst
AssigneeUop LLC
InventorsRichard E. Marinangeli, Jennifer S. Holmgren
Life of this patent
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Abstract
Tetrahedrally charged clays have been found to be active, regenerable catalysts in detergent alkylation, both as delaminated and pillared clays. The pillared saponites and beidellites are especially favored in forming detergent range alkylates using olefins as the alkylating agent to afford products with high monoalkylation selectivity and high linearity. Catalysts can be regenerated by a benzene wash or, after severe deactivation, by a carbon burn.
Claims14
A process for the alkylation of benzene comprising:
- a) reacting under alkylating conditions benzene with one or more linear monoolefins in a feedstock containing at least one linear monoolefin, said alkylating conditions including reacting from about 5 to about 30 molar proportions of total benzene for each molar proportion of total linear monoolefins at a temperature from about 80.degree. C. to about 150.degree. C. and a pressure from about 200 to about 1000 psig, in the presence of a tetrahedrally charged clay as catalyst to obtain alkylated benzenes with an initial conversion of at least 98% of said monoolefins;
- b) continuing reacting benzene and said monoolefins under alkylating conditions until, as a consequence of catalyst deactivation, conversion of said monoolefins decreases to no less than about 80% conversion;
- c) reactivating the deactivated catalyst by heating the catalyst with from about 10 to about 75 volumes of benzene at a temperature from about 100.degree. to about 250.degree. C. for a time sufficient to afford a reactivated catalyst whose activity is sufficient to effect at least 98% conversion of said monoolefins in their reaction with benzene;
- and
- d) repeating stage a).
2 more elements
Dependencies are inferred from the claim text.