Process for hydrotreating resins to lighten color
AssigneeHercules Incorporated
InventorsNorman E. Daughenbaugh, Dane G. Goodfellow
Life of this patent
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Abstract
The color of hydrocarbon resins having carbon-carbon double bonds and containing color bodies is lightened by a hydrotreating process comprising contacting a resin having a weight average molecular weight Mw of 250-10,000 with hydrogen in the presence of a catalyst that promotes the hydrogenation of the color bodies without substantially changing the content of carbon-carbon double bonds in the resin. The preferred catalysts are copper chromite and copper/zinc.
Claims69
A process for lightening the color of noncrystalline hydrocarbon resins having carbon-carbon double bonds and containing color bodies, said process consisting essentially of contacting a noncrystalline hydrocarbon resin having a weight average molecular weight of 250-10,000 with hydrogen in the absence of polymerization catalyst residues and in the presence of a catalyst that promotes the hydrogenation of the color bodies without substantially changing the softening point or the content of carbon-carbon double bonds in the resin, said resin being selected from the group consisting of C-5 hydrocarbon resins, C-9 hydrocarbon resins, mixed C-5/C-9 hydrocarbon resins, vinyl aromatic-modified C-5 hydrocarbon resins, dicyclopentadiene resins, aromatic-modified dicyclopentadiene resins, terpene resins, and terpene-phenolic resins.
A process for preparing a light colored hydrocarbon resin, said process consisting essentially of (1) polymerizing unsaturated monomers to form a noncrystalline hydrocarbon resin having carbon-carbon double bonds and a weight average molecular weight Mw of 250-10,000, and containing color bodies, and (2) contacting the resin with hydrogen in the absence of polymerization catalyst residues and in the presence of a catalyst that promotes the hydrogenation of the color bodies without substantially changing the softening point or the content of carbon-carbon double bonds in the resin, said resin being selected from the group consisting of C-5 hydrocarbon resins, C-9 hydrocarbon resins, mixed C-5/C-9 hydrocarbon resins, vinyl aromatic-modified C-5 hydrocarbon resins, dicyclopentadiene resins, aromatic-modified dicyclopentadiene resins, terpene resins, and terpene-phenolic resins.
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