Production of polysuccinimide
AssigneeDonlar Corporation
InventorDaniel A. Batzel
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Abstract
Polysuccinimide is prepared by reacting an unsaturated C.sub.2 dicarboxylic acid or anhydride thereof, e.g., maleic acid, fumaric acid, and maleic anhydride, with a particulate ammonium salt that is thermally decomposable to liberate ammonia. The reaction is carried out at a temperature which is above the thermal decomposition temperature of the ammonium salt and for a time period which is sufficient for the acid or anhydride to react with the ammonia liberated from the ammonium salt and for polymerization to occur. The present method avoids the prior art problems of controlling ammonia losses and water removal. The product polysuccinimide can be readily hydrolyzed to polyaspartic acid or a salt thereof, if desired.
Claims3
A method for preparing polysuccinimide which comprises:
- (a) forming a reaction admixture by combining particulate maleic anhydride with a particulate ammonium salt that is thermally decomposable at a temperature below the boiling point of liquid maleic anhydride;
- (b) heating said so formed admixture to a reaction temperature above the thermal decomposition temperature of said ammonium salt but below the boiling point of liquid maleic anhydride;
- and
- (c) maintaining said so heated admixture at said reaction temperature for a time period of at least about 15 minutes.
Dependencies are inferred from the claim text.